,
volume 43
,
issue 6
,
pages 352-363
Thiocyanates of rare-earth elements with tetramethylphenanthroline
Publication type: Journal Article
Publication date: 2017-06-10
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Molecular [M(NCS)3(H2O)(Me4Phen)2] · (Me4Phen) · 0.75EtOH and anionic [H(Me4Phen)][М(NCS)4(Me4Phen)2] complexes are synthesized using thiocyanates М(NCS)3 · 6H2O (M = Y, Eu, Tb) and 3,4,7,8-tetramethyl-1,10-phenanthroline (Me4Phen). The complexes are characterized by IR spectroscopy and elemental, X-ray phase, and X-ray diffraction analyses (CIF files CCDC no. 1498178–1498184). The thermoanalytical study shows that the solvate molecules Me4Phen are localized in the internal coordination sphere of the molecular complexes at 195–250°C. The magnetic behavior of the Eu and Tb complexes is governed by the nature of the Ln ion.
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Petrosyants S. P. et al. Thiocyanates of rare-earth elements with tetramethylphenanthroline // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 6. pp. 352-363.
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Petrosyants S. P., Ilyukhin A. B., Dobrokhotova Z. V., Efimov N. N., Novotortsev V. M. Thiocyanates of rare-earth elements with tetramethylphenanthroline // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 6. pp. 352-363.
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TY - JOUR
DO - 10.1134/S1070328417060057
UR - http://link.springer.com/10.1134/S1070328417060057
TI - Thiocyanates of rare-earth elements with tetramethylphenanthroline
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Petrosyants, S P
AU - Ilyukhin, A. B.
AU - Dobrokhotova, Zh V
AU - Efimov, N. N.
AU - Novotortsev, V. M.
PY - 2017
DA - 2017/06/10
PB - Pleiades Publishing
SP - 352-363
IS - 6
VL - 43
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2017_Petrosyants,
author = {S P Petrosyants and A. B. Ilyukhin and Zh V Dobrokhotova and N. N. Efimov and V. M. Novotortsev},
title = {Thiocyanates of rare-earth elements with tetramethylphenanthroline},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2017},
volume = {43},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1070328417060057},
number = {6},
pages = {352--363},
doi = {10.1134/S1070328417060057}
}
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Petrosyants, S. P., et al. “Thiocyanates of rare-earth elements with tetramethylphenanthroline.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 6, Jun. 2017, pp. 352-363. http://link.springer.com/10.1134/S1070328417060057.
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