,
volume 44
,
issue 6
,
pages 410-414
Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis
D M Roitershtein
1, 2
,
M D Dobrokhodov
1
,
A A Vinogradov
1
,
M E Minyaev
1
,
K.A. Lyssenko
3
,
A.V. Churakov
4
,
N P Datskevich
5
,
I V Taidakov
3, 5
,
I E Nifantev
1, 6
4
Publication type: Journal Article
Publication date: 2018-06-14
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Controlled hydrolysis of the terbium cyclopentadienyl complexes results in the formation of the heteroligand tetranuclear terbium complex [{Tb(η5-C5H5)}3{Tb(THF)3}(μ3-Cl)(μ2-Cl)6(μ4-O)] (I), the recrystallization of which from tetrahydrofuran (THF) gives solvatomorph I · 0.5THF (Ia). According to the X-ray structure analysis data (CIF files CCDC 1569329 (I) and 1569330 (Ia)), the complexes are tetrahedral with the μ4-bridging O2– anion at the center of the tetrahedron. The cyclopentadienyl ligand in complex I is shown to act as an “antenna” providing luminescence of the complex.
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Roitershtein D. M. et al. Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 6. pp. 410-414.
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Roitershtein D. M., Dobrokhodov M. D., Vinogradov A. A., Minyaev M. E., Lyssenko K., Churakov A., Datskevich N. P., Taidakov I. V., Nifantev I. E. Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 6. pp. 410-414.
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TY - JOUR
DO - 10.1134/S1070328418060052
UR - http://link.springer.com/10.1134/S1070328418060052
TI - Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Roitershtein, D M
AU - Dobrokhodov, M D
AU - Vinogradov, A A
AU - Minyaev, M E
AU - Lyssenko, K.A.
AU - Churakov, A.V.
AU - Datskevich, N P
AU - Taidakov, I V
AU - Nifantev, I E
PY - 2018
DA - 2018/06/14
PB - Pleiades Publishing
SP - 410-414
IS - 6
VL - 44
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2018_Roitershtein,
author = {D M Roitershtein and M D Dobrokhodov and A A Vinogradov and M E Minyaev and K.A. Lyssenko and A.V. Churakov and N P Datskevich and I V Taidakov and I E Nifantev},
title = {Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2018},
volume = {44},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1070328418060052},
number = {6},
pages = {410--414},
doi = {10.1134/S1070328418060052}
}
Cite this
MLA
Copy
Roitershtein, D. M., et al. “Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysis.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 6, Jun. 2018, pp. 410-414. http://link.springer.com/10.1134/S1070328418060052.