volume 44 issue 11 pages 660-666

Cyano-Bridged d–f Ensembles of the Dysprosium Tetrapyridine Complexes with the Hexacyanoferrate Anion

Publication typeJournal Article
Publication date2018-10-12
scimago Q4
wos Q4
SJR0.189
CiteScore1.7
Impact factor1.1
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of DyX3 · 6H2O (X = NCS, Cl) with 2,2':6',2''-terpyridine (Terpy) and K3Fe(CN)6 in aqueous-alcohol solutions afford cyano-bridged ensembles [Dy(Terpy)(H2O)3Fe(CN)6] · nH2O, [Dy2(Terpy)2(H2O)3(CO3)(NCS)Fe(CN)6] · 4H2O, and [Dy2(Terpy)2(H2O)4(CO3)(NCS)Fe(CN)6] · 11.4H2O. The compounds obtained are identified by the data of elemental analysis, IR spectroscopy, X-ray diffraction analysis, and X-ray structure analysis (CIF files CCDC nos. 1827138–1827140). The study of the magnetic properties of complex [Dy(Terpy)(H2O)3Fe(CN)6] · nH2O shows the low-spin state of Fe3+. The dynamic magnetic behavior of this complex exhibits a slow magnetic relaxation.
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Petrosyants S. P. et al. Cyano-Bridged d–f Ensembles of the Dysprosium Tetrapyridine Complexes with the Hexacyanoferrate Anion // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 11. pp. 660-666.
GOST all authors (up to 50) Copy
Petrosyants S. P., Ilyukhin A. B., Efimov N. N., Novotortsev V. M. Cyano-Bridged d–f Ensembles of the Dysprosium Tetrapyridine Complexes with the Hexacyanoferrate Anion // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 11. pp. 660-666.
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RIS Copy
TY - JOUR
DO - 10.1134/S1070328418110064
UR - http://link.springer.com/10.1134/S1070328418110064
TI - Cyano-Bridged d–f Ensembles of the Dysprosium Tetrapyridine Complexes with the Hexacyanoferrate Anion
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Petrosyants, S P
AU - Ilyukhin, A. B.
AU - Efimov, N. N.
AU - Novotortsev, V. M.
PY - 2018
DA - 2018/10/12
PB - Pleiades Publishing
SP - 660-666
IS - 11
VL - 44
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Petrosyants,
author = {S P Petrosyants and A. B. Ilyukhin and N. N. Efimov and V. M. Novotortsev},
title = {Cyano-Bridged d–f Ensembles of the Dysprosium Tetrapyridine Complexes with the Hexacyanoferrate Anion},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2018},
volume = {44},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S1070328418110064},
number = {11},
pages = {660--666},
doi = {10.1134/S1070328418110064}
}
MLA
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MLA Copy
Petrosyants, S. P., et al. “Cyano-Bridged d–f Ensembles of the Dysprosium Tetrapyridine Complexes with the Hexacyanoferrate Anion.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 11, Oct. 2018, pp. 660-666. http://link.springer.com/10.1134/S1070328418110064.