Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties

Publication type: Journal Article
Publication date: 2019-07-09
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Cadmium compound [Cd(CF3COO)2(Ph3P)2] is synthesized, and its crystal structure is determined. The crystals are monoclinic: space group C2/c, a = 20.318(4), b = 10.432(2), c = 18.661(4) Å, β = 104.18(1)°, V = 3834.8(13) Å3, Z = 4, ρcalcd = 1.495 g/cm3. The Cd atom arranged on the 2-fold crystallographic axis has a distorted octahedral coordination due to four oxygen atoms of crystallographically equivalent trifluoroacetate ligands and two phosphorus atoms of triphenylphosphine. Each fluorine atom of the trifluoroacetate groups is randomly disordered over three equally probable positions. The compound is luminescent.
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Kokunov Yu. V. et al. Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 7. pp. 473-477.
GOST all authors (up to 50) Copy
Kokunov Yu. V., Kovalev V. V., Gorbunova Yu. E., Churakov A., Kozyukhin S. A. Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 7. pp. 473-477.
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TY - JOUR
DO - 10.1134/S1070328419070042
UR - http://link.springer.com/10.1134/S1070328419070042
TI - Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Kokunov, Yu V
AU - Kovalev, V V
AU - Gorbunova, Yu E
AU - Churakov, A.V.
AU - Kozyukhin, S A
PY - 2019
DA - 2019/07/09
PB - Pleiades Publishing
SP - 473-477
IS - 7
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2019_Kokunov,
author = {Yu V Kokunov and V V Kovalev and Yu E Gorbunova and A.V. Churakov and S A Kozyukhin},
title = {Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S1070328419070042},
number = {7},
pages = {473--477},
doi = {10.1134/S1070328419070042}
}
MLA
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Kokunov, Yu. V., et al. “Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 7, Jul. 2019, pp. 473-477. http://link.springer.com/10.1134/S1070328419070042.