,
volume 45
,
issue 10
,
pages 706-711
Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition
Publication type: Journal Article
Publication date: 2019-10-03
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The heterometallic nickel and iron chalcogenide complexes, (η5-C5H5)Ni(MeIm)S(µ2-SnPr)Mn(CO)2(η5-C5H5) (I) and (η5-C5H5)Fe(MeIm)(CO)(µ2-SPh)Mn(CO)2(η5-C5H5) (II), and the cobalt nitrosyl complex (MeIm)Co(NO)2I (IIIa, IIIb) (CIF files CCDC nos. 1911962 (I), 1911963 (II), 1911964 (IIIa), and 1911965 (IIIb)) are synthesized and structurally characterized. According to the data of thermogravimetry and differential scanning calorimetry (TG–DSC), the organic moiety of the molecule of complex I is lost to form the NiMnS residue, whereas ferrocene is formed upon the thermal decomposition of complex II.
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Shapovalov S. S. et al. Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 10. pp. 706-711.
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Shapovalov S. S., Tikhonova O. G., Grigoreva M. O., Skabitskii I. V., Simonenko N. P. Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 10. pp. 706-711.
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TY - JOUR
DO - 10.1134/S1070328419100063
UR - https://doi.org/10.1134/S1070328419100063
TI - Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Grigoreva, M O
AU - Skabitskii, I V
AU - Simonenko, N P
PY - 2019
DA - 2019/10/03
PB - Pleiades Publishing
SP - 706-711
IS - 10
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2019_Shapovalov,
author = {S S Shapovalov and O G Tikhonova and M O Grigoreva and I V Skabitskii and N P Simonenko},
title = {Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S1070328419100063},
number = {10},
pages = {706--711},
doi = {10.1134/S1070328419100063}
}
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MLA
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Shapovalov, S. S., et al. “Metal Complexes with the N-Heterocyclic Ligand: Synthesis, Structures, and Thermal Decomposition.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 10, Oct. 2019, pp. 706-711. https://doi.org/10.1134/S1070328419100063.