,
volume 45
,
issue 11
,
pages 799-803
Lanthanide Complexes Based on 1,3-Dimethylimidazolium-4-Carboxylate: Syntheses and Structures
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of the norzoanemonine zwitterion, 1,3-dimethylimidazolium-4-carboxylate (L), with praseodymium(III), samarium(III), and europium(III) chlorides afford crystals of two types: the isostructural binuclear complexes [Ln2(μ-C6H8N2O2)4(HOCH3)4(H2O)4]Cl6 (Ln = Pr(III) (I) and Eu(III) (II)) and the dimeric samarium complex [Sm2(μ-C6H8N2O2)4(C6H8N2O2)2(H2O)5(OCH3)]Cl5 (III), which are characterized by X-ray diffraction analysis and IR spectroscopy. In complexes I–III (CIF files CCDC nos. 1912829 (I), 1912830 (II), 1912831 (III), the metal atoms are bound by four bridging L molecules without forming the metal–metal bond (the M···M distances are 4.595 Å in I, 4.4637 Å in II, and 4.584 Å in III).
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Shapovalov S. S. et al. Lanthanide Complexes Based on 1,3-Dimethylimidazolium-4-Carboxylate: Syntheses and Structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 11. pp. 799-803.
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Shapovalov S. S., Tikhonova O. G., Grigoreva M. O., Skabitskii I. V., Simonenko N. P. Lanthanide Complexes Based on 1,3-Dimethylimidazolium-4-Carboxylate: Syntheses and Structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 11. pp. 799-803.
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TY - JOUR
DO - 10.1134/S1070328419110071
UR - https://doi.org/10.1134/S1070328419110071
TI - Lanthanide Complexes Based on 1,3-Dimethylimidazolium-4-Carboxylate: Syntheses and Structures
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Grigoreva, M O
AU - Skabitskii, I V
AU - Simonenko, N P
PY - 2019
DA - 2019/11/01
PB - Pleiades Publishing
SP - 799-803
IS - 11
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2019_Shapovalov,
author = {S S Shapovalov and O G Tikhonova and M O Grigoreva and I V Skabitskii and N P Simonenko},
title = {Lanthanide Complexes Based on 1,3-Dimethylimidazolium-4-Carboxylate: Syntheses and Structures},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1070328419110071},
number = {11},
pages = {799--803},
doi = {10.1134/S1070328419110071}
}
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MLA
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Shapovalov, S. S., et al. “Lanthanide Complexes Based on 1,3-Dimethylimidazolium-4-Carboxylate: Syntheses and Structures.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 11, Nov. 2019, pp. 799-803. https://doi.org/10.1134/S1070328419110071.