,
volume 45
,
issue 11
,
pages 788-794
Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of ferrocene and decamethylferrocene with vinyltellurium trichloride Ph(Cl)C= C(Ph)TeCl3 afford unusual co-crystalline salts [Cp2Fe]+Cl–Ph(Cl)C=C(Ph)TeCl2OH (I) and [(C5Me5)2Fe]+Cl–(Ph(Cl)C=C(Ph)TeCl2OH) (II). The Ph(Cl)C=C(Ph)TeCl2OH molecule in these salts is neutral and forms only non-covalent (hydrogen and chalcogen) bonds with the chloride ion. The hydrolytic replacement of a chlorine atom not involved in the three-center four-electron Cl–Te–Cl bond in Ph(Cl)C=C(Ph)TeCl3 is due to the general moisture sensitivity of organic telluriium halides, and the accompanying oxidation of ferrocene is not a necessary condition for the formation of Ph(Cl)C=C(Ph)TeCl2OH (III). (CCDC nos. 1908530 (I), 1908531 (II), 1908532 (III).)
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Total citations:
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Citations from 2024:
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Torubaev Yu. V. et al. Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 11. pp. 788-794.
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Torubaev Yu. V., Lyssenko K., Popova A. Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019. Vol. 45. No. 11. pp. 788-794.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1070328419110095
UR - https://link.springer.com/10.1134/S1070328419110095
TI - Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Torubaev, Yu V
AU - Lyssenko, K.A.
AU - Popova, A.E.
PY - 2019
DA - 2019/11/01
PB - Pleiades Publishing
SP - 788-794
IS - 11
VL - 45
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Torubaev,
author = {Yu V Torubaev and K.A. Lyssenko and A.E. Popova},
title = {Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2019},
volume = {45},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://link.springer.com/10.1134/S1070328419110095},
number = {11},
pages = {788--794},
doi = {10.1134/S1070328419110095}
}
Cite this
MLA
Copy
Torubaev, Yu. V., et al. “Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 11, Nov. 2019, pp. 788-794. https://link.springer.com/10.1134/S1070328419110095.
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