Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 46, issue 12, pages 850-856

Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures

Publication typeJournal Article
Publication date2020-12-09
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.9
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The 18-electron (η4-C4Me4)Co(CO)2TeI2Ph compound noticeably decomposes upon prolonged storage and also unusually transforms into the 17-electron (η4-C4Me4)CoI2(PhTeI) complex (I). The X-ray diffraction study of the molecular and crystal structures of complex I (CIF file CCDC no. 1991837) reveals interesting analogies with the molecular structures of the known metal complexes containing organotellurium halide ligands and with the crystal packing of the related one-component crystals of (η4-C4Me4)Co(СО)2TeI2Ph and (η4-C4Me4)Co(СО)2I and two-component crystals of (η4-C4Me4)Co(СО)2I–1,4-C6H4I2. An analysis of the crystal packing of molecules of complex I elucidates a new supramolecular synthone I···(η4-C4Me4) determining the structural motifs of self-assembly in complex I and related compounds (η4-C4Me4)Co(CO)2I, (η4-C4Me4)Co(CO)2I···1,4-C6H4I2, and (η4-C4Me4)Co(CO)2TeI2Ph. The EPR study of compound I shows that cobalt exists in the low-spin state with the total spin S = 1/2.

Citations by journals

1
2
Journal of Structural Chemistry
Journal of Structural Chemistry, 2, 66.67%
Journal of Structural Chemistry
2 publications, 66.67%
Polyhedron
Polyhedron, 1, 33.33%
Polyhedron
1 publication, 33.33%
1
2

Citations by publishers

1
2
Pleiades Publishing
Pleiades Publishing, 2, 66.67%
Pleiades Publishing
2 publications, 66.67%
Elsevier
Elsevier, 1, 33.33%
Elsevier
1 publication, 33.33%
1
2
  • We do not take into account publications that without a DOI.
  • Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
  • Statistics recalculated weekly.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Torubaev Yu. V. et al. Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 12. pp. 850-856.
GOST all authors (up to 50) Copy
Torubaev Yu. V., Skabitskii I. V., Minin V. V., Ugolkova E. A., Rusina P. V., Shapovalov S. S. Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 12. pp. 850-856.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S1070328420120088
UR - https://doi.org/10.1134%2FS1070328420120088
TI - Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Torubaev, Yu V
AU - Skabitskii, I V
AU - Minin, V V
AU - Ugolkova, E. A.
AU - Rusina, P V
AU - Shapovalov, S S
PY - 2020
DA - 2020/12/09 00:00:00
PB - Pleiades Publishing
SP - 850-856
IS - 12
VL - 46
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
Cite this
BibTex Copy
@article{2020_Torubaev
author = {Yu V Torubaev and I V Skabitskii and V V Minin and E. A. Ugolkova and P V Rusina and S S Shapovalov},
title = {Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2020},
volume = {46},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134%2FS1070328420120088},
number = {12},
pages = {850--856},
doi = {10.1134/S1070328420120088}
}
MLA
Cite this
MLA Copy
Torubaev, Yu. V., et al. “Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 12, Dec. 2020, pp. 850-856. https://doi.org/10.1134%2FS1070328420120088.
Found error?