,
volume 46
,
issue 12
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pages 850-856
Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures
Publication type: Journal Article
Publication date: 2020-12-09
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The 18-electron (η4-C4Me4)Co(CO)2TeI2Ph compound noticeably decomposes upon prolonged storage and also unusually transforms into the 17-electron (η4-C4Me4)CoI2(PhTeI) complex (I). The X-ray diffraction study of the molecular and crystal structures of complex I (CIF file CCDC no. 1991837) reveals interesting analogies with the molecular structures of the known metal complexes containing organotellurium halide ligands and with the crystal packing of the related one-component crystals of (η4-C4Me4)Co(СО)2TeI2Ph and (η4-C4Me4)Co(СО)2I and two-component crystals of (η4-C4Me4)Co(СО)2I–1,4-C6H4I2. An analysis of the crystal packing of molecules of complex I elucidates a new supramolecular synthone I···(η4-C4Me4) determining the structural motifs of self-assembly in complex I and related compounds (η4-C4Me4)Co(CO)2I, (η4-C4Me4)Co(CO)2I···1,4-C6H4I2, and (η4-C4Me4)Co(CO)2TeI2Ph. The EPR study of compound I shows that cobalt exists in the low-spin state with the total spin S = 1/2.
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Torubaev Yu. V. et al. Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 12. pp. 850-856.
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Torubaev Yu. V., Skabitskii I. V., Minin V. V., Ugolkova E. A., Rusina P. V., Shapovalov S. S. Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 12. pp. 850-856.
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TY - JOUR
DO - 10.1134/S1070328420120088
UR - http://link.springer.com/10.1134/S1070328420120088
TI - Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Torubaev, Yu V
AU - Skabitskii, I V
AU - Minin, V V
AU - Ugolkova, E. A.
AU - Rusina, P V
AU - Shapovalov, S S
PY - 2020
DA - 2020/12/09
PB - Pleiades Publishing
SP - 850-856
IS - 12
VL - 46
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2020_Torubaev,
author = {Yu V Torubaev and I V Skabitskii and V V Minin and E. A. Ugolkova and P V Rusina and S S Shapovalov},
title = {Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2020},
volume = {46},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S1070328420120088},
number = {12},
pages = {850--856},
doi = {10.1134/S1070328420120088}
}
Cite this
MLA
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Torubaev, Yu. V., et al. “Unusual Formation of the Paramagnetic Complex (η4-C4Me4)CoI2(PhTeI) and Specific Features of Its Electronic, Molecular, and Crystal Structures.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 12, Dec. 2020, pp. 850-856. http://link.springer.com/10.1134/S1070328420120088.