,
volume 47
,
issue 3
,
pages 165-173
Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine
Publication type: Journal Article
Publication date: 2021-03-21
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The complexes [Tb(Bipy)2(H2O)2Cl2]Cl (I), [Ln(Bipy)(H2O)6]Cl3·2H2O·0.5Bipy (Ln = Dy (II), Yb (IV)), [Er(Bipy)2(H2O)3Cl]Cl2·2H2O (III), and [Yb(Bipy)(H2O)6]Cl3 (V) were prepared using salts LnCl3·6H2O (Ln = Tb, Dy, Er, Yb) and 2,2'-bipyridine (Bipy). The structure of complex V was determined by X-ray diffraction (CIF file CCDC no. 2024688). Magnetic characteristics of the complexes indicate that the replacement of water molecules in the coordination sphere of aqua chlorides by bidentate Bipy ligand gives single-molecule magnets with significant barriers for magnetization reversal, especially in the case of ytterbium compound, ΔE/kB([Yb(Bipy)(H2O)6]Cl3·2H2O·0.5Bipy) = 43 K.
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Petrosyants S. P. et al. Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 3. pp. 165-173.
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Petrosyants S. P., Babeshkin K. A., Ilyukhin A. B., Efimov N. N. Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 3. pp. 165-173.
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RIS
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TY - JOUR
DO - 10.1134/S1070328421030039
UR - http://link.springer.com/10.1134/S1070328421030039
TI - Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Petrosyants, S P
AU - Babeshkin, K A
AU - Ilyukhin, A. B.
AU - Efimov, N. N.
PY - 2021
DA - 2021/03/21
PB - Pleiades Publishing
SP - 165-173
IS - 3
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2021_Petrosyants,
author = {S P Petrosyants and K A Babeshkin and A. B. Ilyukhin and N. N. Efimov},
title = {Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S1070328421030039},
number = {3},
pages = {165--173},
doi = {10.1134/S1070328421030039}
}
Cite this
MLA
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Petrosyants, S. P., et al. “Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 3, Mar. 2021, pp. 165-173. http://link.springer.com/10.1134/S1070328421030039.
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