,
volume 47
,
issue 4
,
pages 244-252
Complexes of Lanthanide (Dy, Er, Yb) Thiocyanates with Tetramethylphenanthroline. Synthesis, Thermolysis, and SMM Properties
Publication type: Journal Article
Publication date: 2021-04-14
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The mononuclear neutral complexes [Ln(Me4Phen)2(H2O)(NCS)3]·Me4Phen·0.75EtOH (Ln = Dy, Er, Yb) were prepared for the first time by the reaction of [Ln(H2O)5(NCS)3]·H2O (Ln = Dy, Er, Yb) with 3,4,7,8-tetramethyl-1,10-phenanthroline (Me4Phen) in ethanol. The products were identified by elemental analysis and powder X-ray diffraction. A thermoanalytical study of the products revealed the transfer of the outer-sphere Me4Phen ligand to the first coordination sphere. The obtained compounds were found to behave as single-molecule magnets.
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Petrosyants S. P. et al. Complexes of Lanthanide (Dy, Er, Yb) Thiocyanates with Tetramethylphenanthroline. Synthesis, Thermolysis, and SMM Properties // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 4. pp. 244-252.
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Petrosyants S. P., Babeshkin K. A., Ilyukhin A. B., Belova E. V., Efimov N. N. Complexes of Lanthanide (Dy, Er, Yb) Thiocyanates with Tetramethylphenanthroline. Synthesis, Thermolysis, and SMM Properties // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 4. pp. 244-252.
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TY - JOUR
DO - 10.1134/S1070328421040060
UR - https://link.springer.com/10.1134/S1070328421040060
TI - Complexes of Lanthanide (Dy, Er, Yb) Thiocyanates with Tetramethylphenanthroline. Synthesis, Thermolysis, and SMM Properties
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Petrosyants, S P
AU - Babeshkin, K A
AU - Ilyukhin, A. B.
AU - Belova, E. V.
AU - Efimov, N. N.
PY - 2021
DA - 2021/04/14
PB - Pleiades Publishing
SP - 244-252
IS - 4
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2021_Petrosyants,
author = {S P Petrosyants and K A Babeshkin and A. B. Ilyukhin and E. V. Belova and N. N. Efimov},
title = {Complexes of Lanthanide (Dy, Er, Yb) Thiocyanates with Tetramethylphenanthroline. Synthesis, Thermolysis, and SMM Properties},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://link.springer.com/10.1134/S1070328421040060},
number = {4},
pages = {244--252},
doi = {10.1134/S1070328421040060}
}
Cite this
MLA
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Petrosyants, S. P., et al. “Complexes of Lanthanide (Dy, Er, Yb) Thiocyanates with Tetramethylphenanthroline. Synthesis, Thermolysis, and SMM Properties.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 4, Apr. 2021, pp. 244-252. https://link.springer.com/10.1134/S1070328421040060.
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