,
volume 47
,
issue 6
,
pages 417-423
Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base
Publication type: Journal Article
Publication date: 2021-06-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of zinc chloride with 2-benzylideneamino-5-methylphenol (LH), a bidentate Schiff base, in 1 : 1 molar ratio in the presence of triethylamine gives the ionic complex [Et3NH]+[LZnCl2]– (I). The reaction between the zinc salt (chloride or acetate) and LH in 1 : 2 ratio results in complete displacement of the zinc salt anions to give bis-o-iminophenolate ZnL2 (II), which exists in the crystalline state as the (ZnL2)2 dimer formed via μ-bridging oxygen atoms of two out of the four o-iminophenolate ligands. The molecular structure of ligand LH and complexes I and (II·CDCl3)2 was established by X-ray diffraction (CIF files CCDC nos. 2052647 (LH), 2052645 (I), 2052646 (II·CDCl3)2).
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Protasenko N. A. et al. Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 6. pp. 417-423.
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Protasenko N. A., Baryshnikova S. V., Astafeva T. V., Cherkasov A. V., Poddelsky A. I. Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 6. pp. 417-423.
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TY - JOUR
DO - 10.1134/S1070328421060038
UR - https://doi.org/10.1134/S1070328421060038
TI - Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Protasenko, N A
AU - Baryshnikova, S V
AU - Astafeva, T V
AU - Cherkasov, A. V.
AU - Poddelsky, A I
PY - 2021
DA - 2021/06/01
PB - Pleiades Publishing
SP - 417-423
IS - 6
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Protasenko,
author = {N A Protasenko and S V Baryshnikova and T V Astafeva and A. V. Cherkasov and A I Poddelsky},
title = {Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070328421060038},
number = {6},
pages = {417--423},
doi = {10.1134/S1070328421060038}
}
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MLA
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Protasenko, N. A., et al. “Mono- and Binuclear Zinc Complexes with a Bidentate Phenol-Containing 2-Benzylideneamino-5-Methylphenol Schiff Base.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 6, Jun. 2021, pp. 417-423. https://doi.org/10.1134/S1070328421060038.