Pleiades Publishing
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
,  том 47 ,  издание 8 ,  страницы 546-550

Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition

Тип публикации: Journal Article
Дата публикации: 2021-08-15
Pleiades Publishing
scimago Q4
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БС2
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Краткое описание
The reaction of (η5-C5H5)Ni(SIMes)Cl with n-propylmercaptane and NEt3 in CH2Cl2 affords the thiolate carbene nickel complex (η5-C5H5)Ni(SIMes)SnPr (I) (SIMes is 1,3-dimesitylimidazol-2-ylidene), which reacts with W(CO)5(THF) to form the heterometallic complex (η5-C5H5)Ni(SIMes)(μ2-SnPr)W(CO)5 (II). The reaction of complex I with (η5-С5H5)Mn(CO)2(THF) affords compound (η5-C5H5)Ni(SIMes)(μ2-SnPr)(η5-С5H5)Mn(CO)2 (III). The structures of compounds I, II, and III are determined by X-ray structure analysis (CIF file CCDC nos. 2024873 (I), 2024874 (II), and 2024875 (III)). According to the data of thermogravimetry and differential scanning calorimetry, the thermal decomposition of complexes II and III occurs stepwise in ranges of 101–500 and 119–550°С, and no ligand elimination is observed.
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Shapovalov S. S. et al. Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 8. pp. 546-550.
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Shapovalov S. S., Tikhonova O. G., Skabitskii I. V., Sakharov S. G., Simonenko N. P. Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 8. pp. 546-550.
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TY - JOUR
DO - 10.1134/S1070328421080066
UR - https://doi.org/10.1134/S1070328421080066
TI - Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Skabitskii, I V
AU - Sakharov, S G
AU - Simonenko, N P
PY - 2021
DA - 2021/08/15
PB - Pleiades Publishing
SP - 546-550
IS - 8
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Shapovalov,
author = {S S Shapovalov and O G Tikhonova and I V Skabitskii and S G Sakharov and N P Simonenko},
title = {Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S1070328421080066},
number = {8},
pages = {546--550},
doi = {10.1134/S1070328421080066}
}
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Shapovalov, S. S., et al. “Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 8, Aug. 2021, pp. 546-550. https://doi.org/10.1134/S1070328421080066.