Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 8, pages 546-550
Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition
Publication type: Journal Article
Publication date: 2021-08-15
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of (η5-C5H5)Ni(SIMes)Cl with n-propylmercaptane and NEt3 in CH2Cl2 affords the thiolate carbene nickel complex (η5-C5H5)Ni(SIMes)SnPr (I) (SIMes is 1,3-dimesitylimidazol-2-ylidene), which reacts with W(CO)5(THF) to form the heterometallic complex (η5-C5H5)Ni(SIMes)(μ2-SnPr)W(CO)5 (II). The reaction of complex I with (η5-С5H5)Mn(CO)2(THF) affords compound (η5-C5H5)Ni(SIMes)(μ2-SnPr)(η5-С5H5)Mn(CO)2 (III). The structures of compounds I, II, and III are determined by X-ray structure analysis (CIF file CCDC nos. 2024873 (I), 2024874 (II), and 2024875 (III)). According to the data of thermogravimetry and differential scanning calorimetry, the thermal decomposition of complexes II and III occurs stepwise in ranges of 101–500 and 119–550°С, and no ligand elimination is observed.
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Applied Organometallic Chemistry
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Applied Organometallic Chemistry
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Wiley
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Shapovalov S. S. et al. Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 8. pp. 546-550.
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Shapovalov S. S., Tikhonova O. G., Skabitskii I. V., Sakharov S. G., Simonenko N. P. Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 8. pp. 546-550.
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TY - JOUR
DO - 10.1134/S1070328421080066
UR - https://doi.org/10.1134%2FS1070328421080066
TI - Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Skabitskii, I V
AU - Sakharov, S G
AU - Simonenko, N P
AU - Shapovalov, S S
AU - Tikhonova, O G
PY - 2021
DA - 2021/08/15 00:00:00
PB - Pleiades Publishing
SP - 546-550
IS - 8
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Shapovalov,
author = {I V Skabitskii and S G Sakharov and N P Simonenko and S S Shapovalov and O G Tikhonova},
title = {Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS1070328421080066},
number = {8},
pages = {546--550},
doi = {10.1134/S1070328421080066}
}
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MLA
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Shapovalov, S. S., et al. “Heterometallic Nickel Complexes with N-Heterocyclic Carbene: Synthesis, Structure, and Thermal Decomposition.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 8, Aug. 2021, pp. 546-550. https://doi.org/10.1134%2FS1070328421080066.