Pleiades Publishing
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
,  volume 47 ,  issue 10 ,  pages 679-686

Ligand Exchange and Pyrazole Deprotonation in the Reaction of Trinuclear Palladium(II) Acetate with Binuclear Zinc Pivalate Pyrazole Pyrazolate

Publication type: Journal Article
Publication date: 2021-10-01
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of Pd3(OOCMe)6 with Zn2(µ-Dmpz)2(HDmpz)2(OOCtBu)2 (HDmpz is 3,5-dimethylpyrazole) in dichloromethane at room temperature induces ligand exchange, accompanied by deprotonation of zinc-coordinated pyrazole to give heterocarboxylate 1D coordination polymer [Zn2(µ-OOCMe)(µ-OOCtBu)3]n (I) and 1,4-dioxane-solvated trinuclear complex Pd3(µ-Dmpz)6⋅C4H8O2 (II). Compounds I and II were studied by chemical analysis, IR spectroscopy, and X-ray diffraction (CIF files CCDC no. 2076508 (I) and no. 2076509 (II) respectively).
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Vargaftik M. et al. Ligand Exchange and Pyrazole Deprotonation in the Reaction of Trinuclear Palladium(II) Acetate with Binuclear Zinc Pivalate Pyrazole Pyrazolate // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 679-686.
GOST all authors (up to 50) Copy
Vargaftik M., Nefedov S. Ligand Exchange and Pyrazole Deprotonation in the Reaction of Trinuclear Palladium(II) Acetate with Binuclear Zinc Pivalate Pyrazole Pyrazolate // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 679-686.
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TY - JOUR
DO - 10.1134/S1070328421100079
UR - https://link.springer.com/10.1134/S1070328421100079
TI - Ligand Exchange and Pyrazole Deprotonation in the Reaction of Trinuclear Palladium(II) Acetate with Binuclear Zinc Pivalate Pyrazole Pyrazolate
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Vargaftik, M.N.
AU - Nefedov, S.E.
PY - 2021
DA - 2021/10/01
PB - Pleiades Publishing
SP - 679-686
IS - 10
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Vargaftik,
author = {M.N. Vargaftik and S.E. Nefedov},
title = {Ligand Exchange and Pyrazole Deprotonation in the Reaction of Trinuclear Palladium(II) Acetate with Binuclear Zinc Pivalate Pyrazole Pyrazolate},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://link.springer.com/10.1134/S1070328421100079},
number = {10},
pages = {679--686},
doi = {10.1134/S1070328421100079}
}
MLA
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MLA Copy
Vargaftik, M.N., et al. “Ligand Exchange and Pyrazole Deprotonation in the Reaction of Trinuclear Palladium(II) Acetate with Binuclear Zinc Pivalate Pyrazole Pyrazolate.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 10, Oct. 2021, pp. 679-686. https://link.springer.com/10.1134/S1070328421100079.