Synthesis, Structure and Magnetic Properties of New Ionic Ni–Yb Nitrate Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline

Publication type: Journal Article
Publication date: 2022-04-12
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Abstract New heterometallic nitrate complexes, namely [Ni(bipy) 3 ][Yb(NO 3 ) 5 ]·0.58MeOH ( I ), [Ni(phen) 3 ][Yb(NO 3 ) 5 ] ( II ) and [Ni(phen) 3 ][Yb(NO 3 ) 5 ]·MeOH ( II ·MeOH), have been prepared and studied. Anions [Yb(NO 3 ) 5 ] 2– in these complexes are the first examples of homoleptic ten-coordinatied Yb complexes. The magnetic behavior of single-phase I and II has been studied in static and dynamic modes. A field-induced slowdown of magnetic relaxation, i.e., properties of single-ion magnets (SIMs), was revealed for I and II . Thus, I and II are rare examples of 3 d −4 f -coordination compounds possessing a discrete structure rather than a joint metal core and demonstrating a slowdown in the relaxation of magnetization. The interplay between the properties of SIM and structural features of I and II was established (CIF CCDC files no. 2103796 ( I ), 2103797 ( II ), 2103798 ( II ·MeOH)).
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Vasilyev P. N. et al. Synthesis, Structure and Magnetic Properties of New Ionic Ni–Yb Nitrate Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 4. pp. 242-249.
GOST all authors (up to 50) Copy
Vasilyev P. N., Gavrikov A. V., Ilyukhin A. B., Efimov N. N. Synthesis, Structure and Magnetic Properties of New Ionic Ni–Yb Nitrate Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 4. pp. 242-249.
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TY - JOUR
DO - 10.1134/S1070328422040066
UR - https://link.springer.com/10.1134/S1070328422040066
TI - Synthesis, Structure and Magnetic Properties of New Ionic Ni–Yb Nitrate Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Vasilyev, P N
AU - Gavrikov, A. V.
AU - Ilyukhin, A. B.
AU - Efimov, N. N.
PY - 2022
DA - 2022/04/12
PB - Pleiades Publishing
SP - 242-249
IS - 4
VL - 48
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2022_Vasilyev,
author = {P N Vasilyev and A. V. Gavrikov and A. B. Ilyukhin and N. N. Efimov},
title = {Synthesis, Structure and Magnetic Properties of New Ionic Ni–Yb Nitrate Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2022},
volume = {48},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://link.springer.com/10.1134/S1070328422040066},
number = {4},
pages = {242--249},
doi = {10.1134/S1070328422040066}
}
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Vasilyev, P. N., et al. “Synthesis, Structure and Magnetic Properties of New Ionic Ni–Yb Nitrate Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 48, no. 4, Apr. 2022, pp. 242-249. https://link.springer.com/10.1134/S1070328422040066.