Open Access
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volume 48
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issue 5
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pages 295-300
Synthesis and Structural Diversity of Gadolinium 1-(o-Methoxyphenyl)-3,4-diphenylcyclopentadienyl Complexes
Publication type: Journal Article
Publication date: 2022-05-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of 1-(o-methoxyphenyl)-3,4-diphenylcyclopentadienyl potassium with gadolinium chloride tetrahydrofuranate gives, depending on the stoichiometry, either tetranuclear complex [{[η5-(Ph2(o-CH3OC6H4)C5H2)Gd(Thf)]2(µ2-Cl)2(µ3-Cl)3K(Thf)}2] (I) or mononuclear complex [(Ph2(o-CH3OC6H4)C5H2)2GdCl] (II) (CIF files CCDC nos. 2116742 (I), 2116741 (II)). In complex I, the oxygen atom of the methoxy group is not coordinated to the gadolinium cation, whereas in complex II, the Gd3+ cation is coordinated to the oxygen atoms of both methoxy groups. Complex II crystallizes in the chiral space group P41212.
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Bardonov D. A. et al. Synthesis and Structural Diversity of Gadolinium 1-(o-Methoxyphenyl)-3,4-diphenylcyclopentadienyl Complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 5. pp. 295-300.
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Bardonov D. A., Lysenko K. A., Nifantev I. E., Roitershtein D. M. Synthesis and Structural Diversity of Gadolinium 1-(o-Methoxyphenyl)-3,4-diphenylcyclopentadienyl Complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 5. pp. 295-300.
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RIS
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TY - JOUR
DO - 10.1134/S1070328422050013
UR - https://link.springer.com/10.1134/S1070328422050013
TI - Synthesis and Structural Diversity of Gadolinium 1-(o-Methoxyphenyl)-3,4-diphenylcyclopentadienyl Complexes
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Bardonov, D A
AU - Lysenko, K A
AU - Nifantev, I E
AU - Roitershtein, D M
PY - 2022
DA - 2022/05/01
PB - Pleiades Publishing
SP - 295-300
IS - 5
VL - 48
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2022_Bardonov,
author = {D A Bardonov and K A Lysenko and I E Nifantev and D M Roitershtein},
title = {Synthesis and Structural Diversity of Gadolinium 1-(o-Methoxyphenyl)-3,4-diphenylcyclopentadienyl Complexes},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2022},
volume = {48},
publisher = {Pleiades Publishing},
month = {may},
url = {https://link.springer.com/10.1134/S1070328422050013},
number = {5},
pages = {295--300},
doi = {10.1134/S1070328422050013}
}
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MLA
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Bardonov, D. A., et al. “Synthesis and Structural Diversity of Gadolinium 1-(o-Methoxyphenyl)-3,4-diphenylcyclopentadienyl Complexes.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 48, no. 5, May. 2022, pp. 295-300. https://link.springer.com/10.1134/S1070328422050013.