Open Access
,
том 48
,
издание 6
,
страницы 353-361
Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling
M A Lavrova
1
,
A M Lunev
1
,
V. E. Goncharenko
1, 2
,
I V Taidakov
2
,
V D Dolzhenko
1
,
Yu A Belousov
1, 2
Тип публикации: Journal Article
Дата публикации: 2022-06-20
scimago Q4
wos Q4
БС2
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Краткое описание
New complex [RuL(Dmdcbp)2]PF6 (I) is synthesized by the consecutive reactions of [Ru-p-cymene]2Cl4 with 3,3',5,5'-tetramethyl-1,1'-biphenyl-4,4'-bipyrazole (L) and 4,4'-dicarboxy-2,2'-bipyridine in a methanol–chloroform medium. The composition of complex I is confirmed by NMR and elemental analysis, and the optical and luminescence properties of the complex are studied. Ligand L is characterized for the first time by X-ray diffraction (CIF file CCDC no. 2118676). Quantum chemical calculations in terms of the density functional theory are performed for the interpretation of the absorption and emission spectra. Complex I is promising for using as a photosensitizer.
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Lavrova M. A. et al. Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 6. pp. 353-361.
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Lavrova M. A., Lunev A. M., Goncharenko V. E., Taidakov I. V., Dolzhenko V. D., Belousov Yu. A. Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 6. pp. 353-361.
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TY - JOUR
DO - 10.1134/S1070328422060033
UR - https://doi.org/10.1134/S1070328422060033
TI - Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Lavrova, M A
AU - Lunev, A M
AU - Goncharenko, V. E.
AU - Taidakov, I V
AU - Dolzhenko, V D
AU - Belousov, Yu A
PY - 2022
DA - 2022/06/20
PB - Pleiades Publishing
SP - 353-361
IS - 6
VL - 48
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2022_Lavrova,
author = {M A Lavrova and A M Lunev and V. E. Goncharenko and I V Taidakov and V D Dolzhenko and Yu A Belousov},
title = {Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2022},
volume = {48},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070328422060033},
number = {6},
pages = {353--361},
doi = {10.1134/S1070328422060033}
}
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Lavrova, M. A., et al. “Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 48, no. 6, Jun. 2022, pp. 353-361. https://doi.org/10.1134/S1070328422060033.