Russian Journal of General Chemistry, volume 79, issue 9, pages 1900-1909

Thermal properties of ligands, salts and metal complexes of linear oligopyrroles

Publication typeJournal Article
Publication date2009-09-01
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor0.9
ISSN10703632, 16083350
General Chemistry
Abstract
The effect of structure on the thermal properties of dipyrrolylmethanes, dipyrrolylmethenes, bis (dipyrrolylmethenes), their salts, and chelates is analyzed proceeding from the results of thermogravimetric analysis. The common tendency is a decrease in the thermal stability of compounds with a disturbed symmetry of alkyl substitution of ligands and with a higher degree of their alkylation, with the increased size of alkyl substituents, with the nitrogen atom in the five-member cycles replaced by S or O. The opposite effect occurs at the change in the mode of attaching methylene spacer in going from 2,2′- to 3,3′-bis(dipyrrolylmethenes). The effects of the themostabilization of the ligands of linear oligopyrroles in the composition of chelates and HBr salts are evaluated quantitatively.

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GOST Copy
Antina E. V. et al. Thermal properties of ligands, salts and metal complexes of linear oligopyrroles // Russian Journal of General Chemistry. 2009. Vol. 79. No. 9. pp. 1900-1909.
GOST all authors (up to 50) Copy
Antina E. V., Gusev G. B., Rumyantsev E. V., Dudina N. A. Thermal properties of ligands, salts and metal complexes of linear oligopyrroles // Russian Journal of General Chemistry. 2009. Vol. 79. No. 9. pp. 1900-1909.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1070363209090163
UR - https://doi.org/10.1134%2FS1070363209090163
TI - Thermal properties of ligands, salts and metal complexes of linear oligopyrroles
T2 - Russian Journal of General Chemistry
AU - Antina, E V
AU - Gusev, G B
AU - Rumyantsev, E V
AU - Dudina, N A
PY - 2009
DA - 2009/09/01 00:00:00
PB - Pleiades Publishing
SP - 1900-1909
IS - 9
VL - 79
SN - 1070-3632
SN - 1608-3350
ER -
BibTex |
Cite this
BibTex Copy
@article{2009_Antina
author = {E V Antina and G B Gusev and E V Rumyantsev and N A Dudina},
title = {Thermal properties of ligands, salts and metal complexes of linear oligopyrroles},
journal = {Russian Journal of General Chemistry},
year = {2009},
volume = {79},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS1070363209090163},
number = {9},
pages = {1900--1909},
doi = {10.1134/S1070363209090163}
}
MLA
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MLA Copy
Antina, E. V., et al. “Thermal properties of ligands, salts and metal complexes of linear oligopyrroles.” Russian Journal of General Chemistry, vol. 79, no. 9, Sep. 2009, pp. 1900-1909. https://doi.org/10.1134%2FS1070363209090163.
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