Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex
2
Indian Technological Institute of Madras, Chennay, India
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Publication type: Journal Article
Publication date: 2010-04-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Reactivity of low-chlorinated congeners of polychlorinated biphenyls in relation to sodiumnaphthalene complex in THF was studied. It was shown that the rate of reduction of these substrates weakly depended on their structure. The regioselectivity of the first stage of reduction of dichlorobiphenyls may be caused by relative stability of the intermediately formed aryl radicals. Kinetic analysis of the processes taking place in the system showed that sodium-naphthalene complex alongside with one-electron reduction of dichlorobiphenyls is involved also in the multi-electron reduction leading directly to biphenyl avoiding the stage of formation of monochlorobiphenyl.
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Boyarskii V. P. et al. Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex // Russian Journal of General Chemistry. 2010. Vol. 80. No. 4. pp. 800-808.
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Boyarskii V. P., Sangaranarayanan M., Khaibulova T. S., Boyarskaya I. A. Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex // Russian Journal of General Chemistry. 2010. Vol. 80. No. 4. pp. 800-808.
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RIS
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TY - JOUR
DO - 10.1134/S1070363210040201
UR - http://link.springer.com/10.1134/S1070363210040201
TI - Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex
T2 - Russian Journal of General Chemistry
AU - Boyarskii, V P
AU - Sangaranarayanan, M.V.
AU - Khaibulova, T Sh
AU - Boyarskaya, I A
PY - 2010
DA - 2010/04/01
PB - Pleiades Publishing
SP - 800-808
IS - 4
VL - 80
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2010_Boyarskii,
author = {V P Boyarskii and M.V. Sangaranarayanan and T Sh Khaibulova and I A Boyarskaya},
title = {Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex},
journal = {Russian Journal of General Chemistry},
year = {2010},
volume = {80},
publisher = {Pleiades Publishing},
month = {apr},
url = {http://link.springer.com/10.1134/S1070363210040201},
number = {4},
pages = {800--808},
doi = {10.1134/S1070363210040201}
}
Cite this
MLA
Copy
Boyarskii, V. P., et al. “Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex.” Russian Journal of General Chemistry, vol. 80, no. 4, Apr. 2010, pp. 800-808. http://link.springer.com/10.1134/S1070363210040201.
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