том 80 издание 4 страницы 800-808

Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex

V P Boyarskii 1
M.V. Sangaranarayanan 2
T Sh Khaibulova 1
I A Boyarskaya 1
Тип публикацииJournal Article
Дата публикации2010-04-01
scimago Q4
wos Q4
БС2
SJR0.179
CiteScore1.4
Impact factor0.8
ISSN10703632, 16083350
General Chemistry
Краткое описание
Reactivity of low-chlorinated congeners of polychlorinated biphenyls in relation to sodiumnaphthalene complex in THF was studied. It was shown that the rate of reduction of these substrates weakly depended on their structure. The regioselectivity of the first stage of reduction of dichlorobiphenyls may be caused by relative stability of the intermediately formed aryl radicals. Kinetic analysis of the processes taking place in the system showed that sodium-naphthalene complex alongside with one-electron reduction of dichlorobiphenyls is involved also in the multi-electron reduction leading directly to biphenyl avoiding the stage of formation of monochlorobiphenyl.
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Russian Journal of General Chemistry
3 публикации, 50%
Journal of Physical Chemistry C
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Materials Today Energy
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Tetrahedron
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Pleiades Publishing
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ГОСТ |
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Boyarskii V. P. et al. Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex // Russian Journal of General Chemistry. 2010. Vol. 80. No. 4. pp. 800-808.
ГОСТ со всеми авторами (до 50) Скопировать
Boyarskii V. P., Sangaranarayanan M., Khaibulova T. S., Boyarskaya I. A. Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex // Russian Journal of General Chemistry. 2010. Vol. 80. No. 4. pp. 800-808.
RIS |
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TY - JOUR
DO - 10.1134/S1070363210040201
UR - http://link.springer.com/10.1134/S1070363210040201
TI - Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex
T2 - Russian Journal of General Chemistry
AU - Boyarskii, V P
AU - Sangaranarayanan, M.V.
AU - Khaibulova, T Sh
AU - Boyarskaya, I A
PY - 2010
DA - 2010/04/01
PB - Pleiades Publishing
SP - 800-808
IS - 4
VL - 80
SN - 1070-3632
SN - 1608-3350
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2010_Boyarskii,
author = {V P Boyarskii and M.V. Sangaranarayanan and T Sh Khaibulova and I A Boyarskaya},
title = {Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex},
journal = {Russian Journal of General Chemistry},
year = {2010},
volume = {80},
publisher = {Pleiades Publishing},
month = {apr},
url = {http://link.springer.com/10.1134/S1070363210040201},
number = {4},
pages = {800--808},
doi = {10.1134/S1070363210040201}
}
MLA
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Boyarskii, V. P., et al. “Reduction of mono- and dichlorobiphenyls with sodium-naphthalene complex.” Russian Journal of General Chemistry, vol. 80, no. 4, Apr. 2010, pp. 800-808. http://link.springer.com/10.1134/S1070363210040201.