Binary system organic base-anode in the oxidative activation of hydrogen sulfide
Publication type: Journal Article
Publication date: 2012-05-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Initiation of the reaction between hydrogen sulfide and aliphatic, aromatic, and heteroaromatic hydrocarbons in acetonitrile using the binary system organic base-anode is described. The reaction of hydrogen sulfide with nitrogen-containing organic bases is studied by means of cyclic voltammetry. The reaction of hydrogen sulfide with triethylamine leads to the formation of thiolate anion. The next step o reaction is electrochemical oxidation of the thiolate anion that to lead thiyl radical formation in situ thiyl radicals. In the presence of binary system on the basis of hydrogen sulfide aliphatic, aromatic, and heteroaromatic thiols and sulfides are formed at room temperature.
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Shinkar E. V. et al. Binary system organic base-anode in the oxidative activation of hydrogen sulfide // Russian Journal of General Chemistry. 2012. Vol. 82. No. 5. pp. 815-818.
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Shinkar E. V., Smolyaninov I. V., Okhlobystin A. O., Berberova N. T. Binary system organic base-anode in the oxidative activation of hydrogen sulfide // Russian Journal of General Chemistry. 2012. Vol. 82. No. 5. pp. 815-818.
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RIS
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TY - JOUR
DO - 10.1134/S1070363212050015
UR - https://doi.org/10.1134/S1070363212050015
TI - Binary system organic base-anode in the oxidative activation of hydrogen sulfide
T2 - Russian Journal of General Chemistry
AU - Shinkar, E V
AU - Smolyaninov, I V
AU - Okhlobystin, A O
AU - Berberova, N T
PY - 2012
DA - 2012/05/01
PB - Pleiades Publishing
SP - 815-818
IS - 5
VL - 82
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2012_Shinkar,
author = {E V Shinkar and I V Smolyaninov and A O Okhlobystin and N T Berberova},
title = {Binary system organic base-anode in the oxidative activation of hydrogen sulfide},
journal = {Russian Journal of General Chemistry},
year = {2012},
volume = {82},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S1070363212050015},
number = {5},
pages = {815--818},
doi = {10.1134/S1070363212050015}
}
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MLA
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Shinkar, E. V., et al. “Binary system organic base-anode in the oxidative activation of hydrogen sulfide.” Russian Journal of General Chemistry, vol. 82, no. 5, May. 2012, pp. 815-818. https://doi.org/10.1134/S1070363212050015.
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