Russian Journal of General Chemistry, volume 82, issue 7, pages 1293-1297
Kinetic stability of complexes of some d-metals with 3,3'- bis(dipyrrolylmethene) in the binary proton-donor solvent acetic acid-benzene
Publication type: Journal Article
Publication date: 2012-07-01
Journal:
Russian Journal of General Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.9
ISSN: 10703632, 16083350
General Chemistry
Abstract
The kinetics of dissociation of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) binuclear homoleptic double-stranded helicates with bis(2,4,7,8,9-pentametyldipyrrolylmethen-3-yl)methane (H2L) of the [M2L2] composition in the binary proton-donor solvent acetic acid-benzene was studied. Protolytic dissociation of the helicates [M2L2] proceeds in accordance with the third order kinetic equation. Effect of the complexing metal nature is manifested in increased kinetic inertness in the following series of the helicates: [Cd2L2] < [Hg2L2] < [Cu2L2] < [Ni2L2] < [Zn2L2] < [Co2L2]. By the lability in similar environmental conditions the helicates [M2L2] are comparable to the metal complexes of distorted porphyrins and are much more inert than dipyrrolylmethenate mononuclear complexes.
Citations by journals
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1
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Kinetics and Catalysis
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Kinetics and Catalysis
1 publication, 20%
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Russian Journal of Inorganic Chemistry
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Russian Journal of Inorganic Chemistry
1 publication, 20%
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Computational and Theoretical Chemistry
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Computational and Theoretical Chemistry
1 publication, 20%
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Molecular Physics
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Molecular Physics
1 publication, 20%
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1
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Citations by publishers
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1
2
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Pleiades Publishing
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Pleiades Publishing
2 publications, 40%
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Elsevier
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Elsevier
1 publication, 20%
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Taylor & Francis
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Taylor & Francis
1 publication, 20%
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1
2
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Antina L. A. et al. Kinetic stability of complexes of some d-metals with 3,3'- bis(dipyrrolylmethene) in the binary proton-donor solvent acetic acid-benzene // Russian Journal of General Chemistry. 2012. Vol. 82. No. 7. pp. 1293-1297.
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Antina L. A., Guseva G. B., Vyugin A. I., Antina E. V. Kinetic stability of complexes of some d-metals with 3,3'- bis(dipyrrolylmethene) in the binary proton-donor solvent acetic acid-benzene // Russian Journal of General Chemistry. 2012. Vol. 82. No. 7. pp. 1293-1297.
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TY - JOUR
DO - 10.1134/S1070363212070195
UR - https://doi.org/10.1134%2FS1070363212070195
TI - Kinetic stability of complexes of some d-metals with 3,3'- bis(dipyrrolylmethene) in the binary proton-donor solvent acetic acid-benzene
T2 - Russian Journal of General Chemistry
AU - Vyugin, A I
AU - Antina, L A
AU - Guseva, G B
AU - Antina, E V
PY - 2012
DA - 2012/07/01 00:00:00
PB - Pleiades Publishing
SP - 1293-1297
IS - 7
VL - 82
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2012_Antina,
author = {A I Vyugin and L A Antina and G B Guseva and E V Antina},
title = {Kinetic stability of complexes of some d-metals with 3,3'- bis(dipyrrolylmethene) in the binary proton-donor solvent acetic acid-benzene},
journal = {Russian Journal of General Chemistry},
year = {2012},
volume = {82},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS1070363212070195},
number = {7},
pages = {1293--1297},
doi = {10.1134/S1070363212070195}
}
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MLA
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Antina, L. A., et al. “Kinetic stability of complexes of some d-metals with 3,3'- bis(dipyrrolylmethene) in the binary proton-donor solvent acetic acid-benzene.” Russian Journal of General Chemistry, vol. 82, no. 7, Jul. 2012, pp. 1293-1297. https://doi.org/10.1134%2FS1070363212070195.