Russian Journal of General Chemistry, том 83, издание 12, номера страниц: 2306-2308

The influence of ms-substitution on the properties of 3,3′- bis(dipyrrolylmethenes) and their coordination compounds

Тип документаJournal Article
Дата публикации2013-12
ИздательPleiades Publishing
Название журналаRussian Journal of General Chemistry
Квартиль по SCImagoQ3
Квартиль по Web of ScienceQ4
Импакт-фактор 20210.78
ISSN10703632, 16083350
General Chemistry
Краткое описание
We have compared the coordination properties of decamethyl-substituted 3,3′-bis-(dipyrrolylmethenes) (H2L) with different ms-spacers separating the dipyrrolylmethene domains: methylene -CH2-, methoxyphenylmethylene -CH(p-C6H4OMe)-, and trifluoromethylmethylene -CH(CF3)-. The stable binuclear homoligand complexes [M2L2] are formed in reactions of the ligands with Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) acetates. In the cases of all H2L ligands the thermodynamic constants of the complex formation reactions increase in the following series: Cu(II) < Cd(II) < Hg(II) < Ni(II) < Co(II) < Zn(II). The change in -CH2- ms-spacer to -CH(p-C6H4OMe)- or -CH(CF3)- results in a decrease in the constant of H2L complex formation by 1–4 orders of magnitude, the cation being the same. The influence of ms-substitution on the stability and luminescence properties of [M2L2] has been discussed.
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1. Dudina N. A. и др. The influence of ms-substitution on the properties of 3,3′-bis(dipyrrolylmethenes) and their coordination compounds // Russian Journal of General Chemistry. 2013. Т. 83. № 12. С. 2306–2308.
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TY - JOUR

DO - 10.1134/s107036321312013x

UR - http://dx.doi.org/10.1134/S107036321312013X

TI - The influence of ms-substitution on the properties of 3,3′-bis(dipyrrolylmethenes) and their coordination compounds

T2 - Russian Journal of General Chemistry

AU - Dudina, N. A.

AU - Antina, E. V.

AU - Guseva, G. B.

AU - V’yugin, A. I.

PY - 2013

DA - 2013/12

PB - Pleiades Publishing Ltd

SP - 2306-2308

IS - 12

VL - 83

SN - 1070-3632

SN - 1608-3350

ER -

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@article{Dudina_2013,

doi = {10.1134/s107036321312013x},

url = {https://doi.org/10.1134%2Fs107036321312013x},

year = 2013,

month = {dec},

publisher = {Pleiades Publishing Ltd},

volume = {83},

number = {12},

pages = {2306--2308},

author = {N. A. Dudina and E. V. Antina and G. B. Guseva and A. I. V'yugin},

title = {The influence of ms-substitution on the properties of 3,3$\prime$-bis(dipyrrolylmethenes) and their coordination compounds},

journal = {Russian Journal of General Chemistry}

}

MLA
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Dudina, N. A., et al. “The Influence of Ms-Substitution on the Properties of 3,3′-Bis(Dipyrrolylmethenes) and Their Coordination Compounds.” Russian Journal of General Chemistry, vol. 83, no. 12, Dec. 2013, pp. 2306–08. Crossref, https://doi.org/10.1134/s107036321312013x.