Reaction of gaseous hydrogen fluoride with the surface of lanthanum chloride solution to form LaF3·nH2O film and microtubes thereof
L B Gulina
1
,
V P Tolstoy
1
Publication type: Journal Article
Publication date: 2014-08-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
We present the first study of the reaction of hydrogen fluoride fed from the air side of the air/LaCl3 aqueous solution interface with lanthanum cations. The reaction yields a 0.5–1.5-μm LaF3·nH2O surface film with hexagonal crystal structure, built of the ordered planar LaF3·nH2O nanocrystals (the crystal thickness of 7–15 nm and surface area of 0.5–2.5 μm2). The nanocrystals are oriented perpendicular to the interphase boundary, and their packing gets looser towards the solution side of the film. Upon drying in air, the LaF3·nH2O film rolls up to form microtubes 20–100 μm in diameter and up to 2 mm long. The microtubes are likely formed due to the contraction forces developing upon drying in the lower, loosest part of the wet film.
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Total citations:
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Citations from 2025:
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GOST
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Gulina L. B., Tolstoy V. P. Reaction of gaseous hydrogen fluoride with the surface of lanthanum chloride solution to form LaF3·nH2O film and microtubes thereof // Russian Journal of General Chemistry. 2014. Vol. 84. No. 8. pp. 1472-1475.
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Gulina L. B., Tolstoy V. P. Reaction of gaseous hydrogen fluoride with the surface of lanthanum chloride solution to form LaF3·nH2O film and microtubes thereof // Russian Journal of General Chemistry. 2014. Vol. 84. No. 8. pp. 1472-1475.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1070363214080039
UR - https://doi.org/10.1134/S1070363214080039
TI - Reaction of gaseous hydrogen fluoride with the surface of lanthanum chloride solution to form LaF3·nH2O film and microtubes thereof
T2 - Russian Journal of General Chemistry
AU - Gulina, L B
AU - Tolstoy, V P
PY - 2014
DA - 2014/08/01
PB - Pleiades Publishing
SP - 1472-1475
IS - 8
VL - 84
SN - 1070-3632
SN - 1608-3350
ER -
Cite this
BibTex (up to 50 authors)
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@article{2014_Gulina,
author = {L B Gulina and V P Tolstoy},
title = {Reaction of gaseous hydrogen fluoride with the surface of lanthanum chloride solution to form LaF3·nH2O film and microtubes thereof},
journal = {Russian Journal of General Chemistry},
year = {2014},
volume = {84},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S1070363214080039},
number = {8},
pages = {1472--1475},
doi = {10.1134/S1070363214080039}
}
Cite this
MLA
Copy
Gulina, L. B., and V P Tolstoy. “Reaction of gaseous hydrogen fluoride with the surface of lanthanum chloride solution to form LaF3·nH2O film and microtubes thereof.” Russian Journal of General Chemistry, vol. 84, no. 8, Aug. 2014, pp. 1472-1475. https://doi.org/10.1134/S1070363214080039.
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