Redox transformations and antiradical activity of triarylantimony(V) 3,6-di-tert-butyl-4,5-dimethoxycatecholates
Publication type: Journal Article
Publication date: 2014-09-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Triarylantimony(V) catecholate complexes were synthesized by the oxidative addition of 3,6-di-tert-butyl-4,5-dimethoxy-o-benzoquinone to triarylstibines. The electrochemical properties and antiradical activity of the synthesized compounds were studied. According to cyclic viltammetry data, the complexes are oxidized via two consecutive quasi-reversible stages. Introduction of halogen atoms in para-position of phenyl groups at Sb(V) causes anodic shifts of the oxidation potentials and enhances stability of the mono- and dicationic forms of the compounds, which form in the course of electrochemical transformations. Triarylantimony(V) catecholate complexes exhibit appreciable antiradical activity in the auto-oxidation of oleic acid. In was found that the inhibitory activity of the complexes depends on their redox potential.
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Smolyaninov I. V. et al. Redox transformations and antiradical activity of triarylantimony(V) 3,6-di-tert-butyl-4,5-dimethoxycatecholates // Russian Journal of General Chemistry. 2014. Vol. 84. No. 9. pp. 1761-1766.
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Smolyaninov I. V., Poddelskii A. I., Smolyaninova S. A., Movchan N. O. Redox transformations and antiradical activity of triarylantimony(V) 3,6-di-tert-butyl-4,5-dimethoxycatecholates // Russian Journal of General Chemistry. 2014. Vol. 84. No. 9. pp. 1761-1766.
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RIS
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TY - JOUR
DO - 10.1134/S1070363214090205
UR - https://doi.org/10.1134/S1070363214090205
TI - Redox transformations and antiradical activity of triarylantimony(V) 3,6-di-tert-butyl-4,5-dimethoxycatecholates
T2 - Russian Journal of General Chemistry
AU - Smolyaninov, I V
AU - Poddelskii, A I
AU - Smolyaninova, S A
AU - Movchan, N O
PY - 2014
DA - 2014/09/01
PB - Pleiades Publishing
SP - 1761-1766
IS - 9
VL - 84
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2014_Smolyaninov,
author = {I V Smolyaninov and A I Poddelskii and S A Smolyaninova and N O Movchan},
title = {Redox transformations and antiradical activity of triarylantimony(V) 3,6-di-tert-butyl-4,5-dimethoxycatecholates},
journal = {Russian Journal of General Chemistry},
year = {2014},
volume = {84},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1070363214090205},
number = {9},
pages = {1761--1766},
doi = {10.1134/S1070363214090205}
}
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MLA
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Smolyaninov, I. V., et al. “Redox transformations and antiradical activity of triarylantimony(V) 3,6-di-tert-butyl-4,5-dimethoxycatecholates.” Russian Journal of General Chemistry, vol. 84, no. 9, Sep. 2014, pp. 1761-1766. https://doi.org/10.1134/S1070363214090205.
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