Russian Journal of General Chemistry

, volume 84 , issue 11 , pages 2107-2113

Thermo-oxidative degradation of styryl derivatives of pyridine-N-oxides

S N Golubev ¹

N. Sh. Lebedeva ¹

Yu. A. Gubarev ¹

A I Vyugin ¹

V.P. Andreev ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences, Ivanovo, Russia |

Petrozavodsk State University, Petrozavodsk, Russia |

Publication type: Journal Article

Publication date: 2014-11-01

Pleiades Publishing

Russian Journal of General Chemistry

scimago Q4

wos Q4

SJR: 0.179

CiteScore: 1.4

Impact factor: 0.8

ISSN: 10703632, 16083350

DOI: 10.1134/S1070363214110115

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General Chemistry

Abstract

Kinetic parameters of thermo-oxidative degradation of various derivatives of pyridine-N-oxide have been calculated. Thermo-oxidative degradation is a multi-stage process. 4-Substituted pyridine-N-oxides are more thermally stable than the 2-substituted isomers. Stability of 4-substituted pyridine-N-oxides towards thermo-oxidation is enhanced in the presence of electron-donating ability of the substituent. In the case of 4-styrylpyridine-N-oxide, the rate-limiting stage of thermo-oxidation is a chemical reaction; for other studied compounds, the limiting stage is free nucleation and further nuclei growth.

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Golubev S. N. et al. Thermo-oxidative degradation of styryl derivatives of pyridine-N-oxides // Russian Journal of General Chemistry. 2014. Vol. 84. No. 11. pp. 2107-2113.

GOST all authors (up to 50) Copy

Golubev S. N., Lebedeva N. S., Gubarev Y. A., Vyugin A. I., Andreev V. Thermo-oxidative degradation of styryl derivatives of pyridine-N-oxides // Russian Journal of General Chemistry. 2014. Vol. 84. No. 11. pp. 2107-2113.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S1070363214110115

UR - https://doi.org/10.1134/S1070363214110115

TI - Thermo-oxidative degradation of styryl derivatives of pyridine-N-oxides

T2 - Russian Journal of General Chemistry

AU - Golubev, S N

AU - Lebedeva, N. Sh.

AU - Gubarev, Yu. A.

AU - Vyugin, A I

AU - Andreev, V.P.

PY - 2014

DA - 2014/11/01

PB - Pleiades Publishing

SP - 2107-2113

IS - 11

VL - 84

SN - 1070-3632

SN - 1608-3350

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2014_Golubev,

author = {S N Golubev and N. Sh. Lebedeva and Yu. A. Gubarev and A I Vyugin and V.P. Andreev},

title = {Thermo-oxidative degradation of styryl derivatives of pyridine-N-oxides},

journal = {Russian Journal of General Chemistry},

year = {2014},

volume = {84},

publisher = {Pleiades Publishing},

month = {nov},

url = {https://doi.org/10.1134/S1070363214110115},

number = {11},

pages = {2107--2113},

doi = {10.1134/S1070363214110115}

}

MLA

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Golubev, S. N., et al. “Thermo-oxidative degradation of styryl derivatives of pyridine-N-oxides.” Russian Journal of General Chemistry, vol. 84, no. 11, Nov. 2014, pp. 2107-2113. https://doi.org/10.1134/S1070363214110115.