Theoretical study of the structure of acyclic diaminocarbene ligands in Pd(II) complexes
Publication type: Journal Article
Publication date: 2015-04-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
The electronic and steric features of acyclic aminohydrazinocarbene ligands in palladium(II) complexes are studied by the DFT method. It was found that most of the studied complexes prefer an amphi-2 conformation over all the other possible conformations. At the same time, in the ligand containing a hydrazide fragment more stable is a syn conformation. The basicity and nucleophilicity of the title ligands are much higher compared to the respective characteristics of the triphenylphosphine ligand and close to those of bis-(diisopropylamino)carbene.
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Boyarskaya I. A., Boyarskii V. P. Theoretical study of the structure of acyclic diaminocarbene ligands in Pd(II) complexes // Russian Journal of General Chemistry. 2015. Vol. 85. No. 4. pp. 894-898.
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Boyarskaya I. A., Boyarskii V. P. Theoretical study of the structure of acyclic diaminocarbene ligands in Pd(II) complexes // Russian Journal of General Chemistry. 2015. Vol. 85. No. 4. pp. 894-898.
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RIS
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TY - JOUR
DO - 10.1134/S1070363215040222
UR - https://doi.org/10.1134/S1070363215040222
TI - Theoretical study of the structure of acyclic diaminocarbene ligands in Pd(II) complexes
T2 - Russian Journal of General Chemistry
AU - Boyarskaya, I A
AU - Boyarskii, V P
PY - 2015
DA - 2015/04/01
PB - Pleiades Publishing
SP - 894-898
IS - 4
VL - 85
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2015_Boyarskaya,
author = {I A Boyarskaya and V P Boyarskii},
title = {Theoretical study of the structure of acyclic diaminocarbene ligands in Pd(II) complexes},
journal = {Russian Journal of General Chemistry},
year = {2015},
volume = {85},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S1070363215040222},
number = {4},
pages = {894--898},
doi = {10.1134/S1070363215040222}
}
Cite this
MLA
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Boyarskaya, I. A., and V P Boyarskii. “Theoretical study of the structure of acyclic diaminocarbene ligands in Pd(II) complexes.” Russian Journal of General Chemistry, vol. 85, no. 4, Apr. 2015, pp. 894-898. https://doi.org/10.1134/S1070363215040222.
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