Russian Journal of General Chemistry

, volume 85 , issue 11 , pages 2541-2546

Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium

S A Krasko ^{1, 2}

S S Zlotskii ¹

V P Boyarskii ¹

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St. Petersburg state University, St. Petersburg, Russia |

Ufa State Petroleum technical University, Ufa, Russia |

Publication type: Journal Article

Publication date: 2015-11-01

Pleiades Publishing

Russian Journal of General Chemistry

scimago Q4

wos Q4

SJR: 0.179

CiteScore: 1.4

Impact factor: 0.8

ISSN: 10703632, 16083350

DOI: 10.1134/S1070363215110079

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General Chemistry

Abstract

Relative activity of halogenated arenes, alkanes, and alkanes in the Suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium has been investigated. Under all the investigated conditions, 4-iodoanisole has been more active than the alkyl halides. The reaction with 4-methyl-1-(chloromethyl)benzene has afforded the target 4-methyl-1-(phenylmethyl)benzene along with significant amount of by-products; other alkyl and cycloalkyl halides do not participate into the cross-coupling reaction. Ethanol has been found the most suitable solvent for the reaction. The reaction in acetonitrile provides noticeable yield of the products only in the presence of polyethylene glycol and water.

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Kinzhalov Mikhail

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DSc in Chemistry, associate professor

98 publications, 1 926 citations

h-index: 28

National Research Tomsk Polytechnic University

Saint Petersburg State University

Research interests

Coordination Chemistry

Non-covalent Interactions

Organic Chemistry

Organometallic Chemistry

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Krasko S. A. et al. Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium // Russian Journal of General Chemistry. 2015. Vol. 85. No. 11. pp. 2541-2546.

GOST all authors (up to 50) Copy

Krasko S. A., Zlotskii S. S., Boyarskii V. P. Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium // Russian Journal of General Chemistry. 2015. Vol. 85. No. 11. pp. 2541-2546.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S1070363215110079

UR - https://doi.org/10.1134/S1070363215110079

TI - Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium

T2 - Russian Journal of General Chemistry

AU - Krasko, S A

AU - Zlotskii, S S

AU - Boyarskii, V P

PY - 2015

DA - 2015/11/01

PB - Pleiades Publishing

SP - 2541-2546

IS - 11

VL - 85

SN - 1070-3632

SN - 1608-3350

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2015_Krasko,

author = {S A Krasko and S S Zlotskii and V P Boyarskii},

title = {Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium},

journal = {Russian Journal of General Chemistry},

year = {2015},

volume = {85},

publisher = {Pleiades Publishing},

month = {nov},

url = {https://doi.org/10.1134/S1070363215110079},

number = {11},

pages = {2541--2546},

doi = {10.1134/S1070363215110079}

}

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Krasko, S. A., et al. “Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium.” Russian Journal of General Chemistry, vol. 85, no. 11, Nov. 2015, pp. 2541-2546. https://doi.org/10.1134/S1070363215110079.