Absorption and luminescence spectra and photodecomposition of zinc(II) complex with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane in solution and polymer matrix
Publication type: Journal Article
Publication date: 2016-02-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
New polymeric materials containing dinuclear double-stranded zinc(II) helicate with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane have been prepared on the basis of poly(methyl methacrylate) and tetraethoxysilane. The zinc(II) complex [Zn2L2] retains its fluorescence properties in a poly(methyl methacrylate) film. The photostability of [Zn2L2] in poly(methyl methacrylate) is higher by a factor of ≈2.5 than in the benzene solution. Conditions have been found for the preparation of [Zn2L2]-doped silicate matrix based on tetraethoxysilane via the sol–gel method. The [Zn2L2] complex in the tetraethoxysilane solid matrix shows a weak fluorescence with its maximum at λ = 545–549 nm.
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Dudina N. A., Antina L. A., Antina E. V. Absorption and luminescence spectra and photodecomposition of zinc(II) complex with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane in solution and polymer matrix // Russian Journal of General Chemistry. 2016. Vol. 86. No. 2. pp. 349-355.
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Dudina N. A., Antina L. A., Antina E. V. Absorption and luminescence spectra and photodecomposition of zinc(II) complex with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane in solution and polymer matrix // Russian Journal of General Chemistry. 2016. Vol. 86. No. 2. pp. 349-355.
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TY - JOUR
DO - 10.1134/S1070363216020250
UR - https://doi.org/10.1134/S1070363216020250
TI - Absorption and luminescence spectra and photodecomposition of zinc(II) complex with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane in solution and polymer matrix
T2 - Russian Journal of General Chemistry
AU - Dudina, N A
AU - Antina, L A
AU - Antina, E V
PY - 2016
DA - 2016/02/01
PB - Pleiades Publishing
SP - 349-355
IS - 2
VL - 86
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2016_Dudina,
author = {N A Dudina and L A Antina and E V Antina},
title = {Absorption and luminescence spectra and photodecomposition of zinc(II) complex with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane in solution and polymer matrix},
journal = {Russian Journal of General Chemistry},
year = {2016},
volume = {86},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S1070363216020250},
number = {2},
pages = {349--355},
doi = {10.1134/S1070363216020250}
}
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Dudina, N. A., et al. “Absorption and luminescence spectra and photodecomposition of zinc(II) complex with bis(1,2,3,7,9-pentamethyldipyrrin-8-yl)methane in solution and polymer matrix.” Russian Journal of General Chemistry, vol. 86, no. 2, Feb. 2016, pp. 349-355. https://doi.org/10.1134/S1070363216020250.