Regioselectivity of the methanolysis of polychlorinated biphenyls
Publication type: Journal Article
Publication date: 2016-10-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Regioselectivity of the methanolysis of lower polychlorinated biphenyls with sodium methoxide in a mixture of methanol and DMSO at 100–130°С was studied. It was found that 2,4,4'-tricholobiphenyl is much more reactive than 2,4-dichlorobiphenyl. This results in different mechanisms of substitution. 2,4-Dichlorobiphenyl reacts with sodium methoxide by the elimination–addition mechanism to form four monosubstitution products in comparable quantities. 2,4,4'-Trichlorobiphenyl reacts with the methodixe ion by the classical SNAr mechanism, with preferential substitution of the 2-chlorine atom.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Russian Journal of General Chemistry
2 publications, 40%
|
|
|
Russian Journal of Organic Chemistry
1 publication, 20%
|
|
|
Organic Reaction Mechanisms
1 publication, 20%
|
|
|
Russian Chemical Reviews
1 publication, 20%
|
|
|
1
2
|
Publishers
|
1
2
3
|
|
|
Pleiades Publishing
3 publications, 60%
|
|
|
Wiley
1 publication, 20%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 20%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
5
Total citations:
5
Citations from 2024:
1
(20%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Khaibulova T. S. et al. Regioselectivity of the methanolysis of polychlorinated biphenyls // Russian Journal of General Chemistry. 2016. Vol. 86. No. 10. pp. 2318-2324.
GOST all authors (up to 50)
Copy
Khaibulova T. S., Boyarskaya I. A., Polukeev V. A., Boyarskii V. P. Regioselectivity of the methanolysis of polychlorinated biphenyls // Russian Journal of General Chemistry. 2016. Vol. 86. No. 10. pp. 2318-2324.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1070363216100121
UR - http://link.springer.com/10.1134/S1070363216100121
TI - Regioselectivity of the methanolysis of polychlorinated biphenyls
T2 - Russian Journal of General Chemistry
AU - Khaibulova, T Sh
AU - Boyarskaya, I A
AU - Polukeev, V A
AU - Boyarskii, V P
PY - 2016
DA - 2016/10/01
PB - Pleiades Publishing
SP - 2318-2324
IS - 10
VL - 86
SN - 1070-3632
SN - 1608-3350
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Khaibulova,
author = {T Sh Khaibulova and I A Boyarskaya and V A Polukeev and V P Boyarskii},
title = {Regioselectivity of the methanolysis of polychlorinated biphenyls},
journal = {Russian Journal of General Chemistry},
year = {2016},
volume = {86},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S1070363216100121},
number = {10},
pages = {2318--2324},
doi = {10.1134/S1070363216100121}
}
Cite this
MLA
Copy
Khaibulova, T. Sh, et al. “Regioselectivity of the methanolysis of polychlorinated biphenyls.” Russian Journal of General Chemistry, vol. 86, no. 10, Oct. 2016, pp. 2318-2324. http://link.springer.com/10.1134/S1070363216100121.
Profiles