Coupling of Bis(xylylisocyanide) Palladium(II) Complex with 1,2,4-Thiadiazole-5-amines
Тип публикации: Journal Article
Дата публикации: 2018-04-01
scimago Q4
wos Q4
БС2
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Краткое описание
The coupling of bis(xylylisocyanide) complex of Pd(II) with 1,2,4-thiadiazole-5-amines leads to the formation of an equilibrium mixture of the binuclear complexes. In each of the studied cases, one of the formed complexes is the kinetic product, and the other one is the thermodynamic product. The complexes which are thermodynamic products have been isolated in the pure form and characterized by means of high-resolution mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction analysis. NMR study of the regioisomerization in a solution has revealed that the relative stability of the thermodynamic products in comparison with the kinetic ones is higher than for the corresponding regioisomers containing 1,3-thiazole or 1,3,4- thiadiazole fragment.
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Mikherdov A. S. et al. Coupling of Bis(xylylisocyanide) Palladium(II) Complex with 1,2,4-Thiadiazole-5-amines // Russian Journal of General Chemistry. 2018. Vol. 88. No. 4. pp. 713-720.
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Mikherdov A. S., Tiuftiakov N. Yu., Polukeev V. A., Boyarskii V. P. Coupling of Bis(xylylisocyanide) Palladium(II) Complex with 1,2,4-Thiadiazole-5-amines // Russian Journal of General Chemistry. 2018. Vol. 88. No. 4. pp. 713-720.
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TY - JOUR
DO - 10.1134/S1070363218040151
UR - https://doi.org/10.1134/S1070363218040151
TI - Coupling of Bis(xylylisocyanide) Palladium(II) Complex with 1,2,4-Thiadiazole-5-amines
T2 - Russian Journal of General Chemistry
AU - Mikherdov, A S
AU - Tiuftiakov, N Yu
AU - Polukeev, V A
AU - Boyarskii, V P
PY - 2018
DA - 2018/04/01
PB - Pleiades Publishing
SP - 713-720
IS - 4
VL - 88
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2018_Mikherdov,
author = {A S Mikherdov and N Yu Tiuftiakov and V A Polukeev and V P Boyarskii},
title = {Coupling of Bis(xylylisocyanide) Palladium(II) Complex with 1,2,4-Thiadiazole-5-amines},
journal = {Russian Journal of General Chemistry},
year = {2018},
volume = {88},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S1070363218040151},
number = {4},
pages = {713--720},
doi = {10.1134/S1070363218040151}
}
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MLA
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Mikherdov, A. S., et al. “Coupling of Bis(xylylisocyanide) Palladium(II) Complex with 1,2,4-Thiadiazole-5-amines.” Russian Journal of General Chemistry, vol. 88, no. 4, Apr. 2018, pp. 713-720. https://doi.org/10.1134/S1070363218040151.
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