Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine
Publication type: Journal Article
Publication date: 2018-06-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
A 2,4,6-trisubstituted pyrimidine including a 2-(1H-indol-1-yl) substituent was synthesized by the reaction of 1-ferrocenyl-3-(2-chloroimidazo[1,2-a]pyridin-3-yl)propanone with 2,5-dimethoxytetrahydrofuran. The structure of the synthesized compound was confirmed by IR and 1Н NMR spectroscopy, and X-ray diffraction analysis. It has been shown that the ferrocene-containing compounds synthesized in the present work all demonstrate intramolecular charge transfer which is evidenced by the observation of the corresponding absorption bands with λmaxabs > 480 nm. The oxidation potential of ferrocene (EoxFc) in all the compounds is higher than 700 mV.
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Antufeva A. D. et al. Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine // Russian Journal of General Chemistry. 2018. Vol. 88. No. 6. pp. 1103-1107.
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Antufeva A. D., Akhmatzyanova D. R., Dmitriev M. V., Shklyaeva E. V., Abashev G. G. Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine // Russian Journal of General Chemistry. 2018. Vol. 88. No. 6. pp. 1103-1107.
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TY - JOUR
DO - 10.1134/S1070363218060099
UR - https://doi.org/10.1134/S1070363218060099
TI - Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine
T2 - Russian Journal of General Chemistry
AU - Antufeva, A D
AU - Akhmatzyanova, D R
AU - Dmitriev, M V
AU - Shklyaeva, E V
AU - Abashev, G. G.
PY - 2018
DA - 2018/06/01
PB - Pleiades Publishing
SP - 1103-1107
IS - 6
VL - 88
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2018_Antufeva,
author = {A D Antufeva and D R Akhmatzyanova and M V Dmitriev and E V Shklyaeva and G. G. Abashev},
title = {Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine},
journal = {Russian Journal of General Chemistry},
year = {2018},
volume = {88},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070363218060099},
number = {6},
pages = {1103--1107},
doi = {10.1134/S1070363218060099}
}
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Antufeva, A. D., et al. “Synthesis and Structure of 2-(1Н-Indol-1-yl)-6-ferrocenyl-4-(2-chloroimidazo[1,2-a]pyridin-3-yl)pyrimidine.” Russian Journal of General Chemistry, vol. 88, no. 6, Jun. 2018, pp. 1103-1107. https://doi.org/10.1134/S1070363218060099.
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