Russian Journal of General Chemistry, том 88, издание 6, номера страниц: 1172-1179

Effect of Structure and Medium on Photostability of Halogenated Boron(III), Zinc(II), and Cadmium(II) Dipyrromethenates

Тип документаJournal Article
Дата публикации2018-06
ИздательPleiades Publishing
Название журналаRussian Journal of General Chemistry
Квартиль по SCImagoQ3
Квартиль по Web of ScienceQ4
Импакт-фактор 20210.78
ISSN10703632, 16083350
General Chemistry
Краткое описание
Photostability of B(III), Zn(II), Cd(II) complexes with monoiodo- and dibromosubstituted dipyrromethenes [BF2L] and [ML2] in benzene and cyclohexane solutions is studied. It is found that the mechanism of destruction of the dyes under UV radiation is based on participation of singlet oxygen generated by the excited triplet state of the dye. Singlet oxygen enters the oxidation reactions of the pigment molecules leading to accumulation of colorless products based on di-, monopyrrol, and smaller fragments. Initial stages of the process include the reactions of dehalogenation of the dye molecules and are accompanied by enhancement of the fluorescence of the formed alkyl-substituted dipyrromethenates. The photostability of boron complexes [BF2L] is up to 32 times higher as compared to that of [ZnL2] and [CdL2]. The replacement of 4-iododipyrromethene ligands in [BF2L] and [ML2] by 5,5'-or 4,4'-dibromo-substituted ligands increases photostability of the dyes. The stability of the dyes against UV irradiation substantially decreases in benzene with respect to cyclohexane due to enhancement of polarization of the chromophore systems of dipyrromethene ligands because of their solvation with benzene (π–π-stacking).
Пристатейные ссылки: 19
Цитируется в публикациях: 2
meso-Acetoxymethyl BODIPY dyes for photodynamic therapy: improved photostability of singlet oxygen photosensitizers.
Lincoln R., Durantini A.M., Greene L.E., Martínez S.R., Knox R., Becerra M.C., Cosa G.
Q2 Photochemical and Photobiological Sciences 2017 цитирований: 31
Synthesis, spectral luminescent properties, and photostability of monoiodo- and dibromo-substituted BF2-dipyrrinates
Nuraneeva E.N., Guseva G.B., Antina E.V., Kuznetsova R.T., Berezin M.B., V’yugin A.I.
Q3 Russian Journal of General Chemistry 2016 цитирований: 13
Synthesis and luminescent properties of zinc(II) complexes with iodo- and bromosubstituted 2,2′-dipyrrines
Nuraneeva E.N., Guseva G.B., Antina E.V., Berezin M.B., V’yugin A.I.
Q2 Journal of Luminescence 2016 цитирований: 11
A quantum chemical study of the molecular structure of zinc(II) and boron(II) complexes with monoiodo and dibromo substituted dipyrrines
Guseva G.B., Antina E.V., Ksenofontov A.A., Nuraneeva E.N.
Q4 Journal of Structural Chemistry 2016 цитирований: 15
Preparation, spectral and thermal properties of Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) complexes with iodosubstituted 2,2′-dipyrrolylmethene
Guseva G.B., Antina E.V., Beresin M.B., V’yugin A.I., Nuraneeva E.N.
Q3 Russian Journal of General Chemistry 2013 цитирований: 14
Optical characteristics of new luminophores based on boron-fluoride complexes of substituted dipyrromethenes
Yutanova S.L., Kuznetsova R.T., Aksenova Y.V., Tel’minov E.N., Berezin M.B.
Q3 Russian Physics Journal 2013 цитирований: 13
Modulating the singlet oxygen generation property of meso-β directly linked BODIPY dimers.
Pang W., Zhang X., Zhou J., Yu C., Hao E., Jiao L.
Q1 Chemical Communications 2012 цитирований: 95
Singlet oxygen generation by novel NIR BODIPY dyes.
Awuah S.G., Polreis J., Biradar V., You Y.
Q1 Organic Letters 2011 цитирований: 192
In vitro and in vivo photocytotoxicity of boron dipyrromethene derivatives for photodynamic therapy.
Lim S.H., Thivierge C., Nowak-Sliwinska P., Han J., van den Bergh H., Wagnières G., Burgess K., Lee H.B.
Q1 Journal of Medicinal Chemistry 2010 цитирований: 274
Unusual electronic structure of first row transition metal complexes featuring redox-active dipyrromethane ligands.
King E.R., Betley T.A.
Q1 Journal of the American Chemical Society 2009 цитирований: 34
Sensitizing effect of Z,Z-bilirubin IXα and its photoproducts on enzymes in model solutions
Plavskii V.Y., Mostovnikov V.A., Tret’yakova A.I., Mostovnikova G.R.
Q4 Journal of Applied Spectroscopy 2008 цитирований: 8
Two-photon pumped lasing stilbene-typechromophores containing various terminal donor groups: relationship betweenlasing efficiency and intramolecular charge transfer
Wang X., Zhou Y., Yu W., Wang C., Fang Q., Jiang M., Lei H., Wang H.
Q1 Journal of Materials Chemistry 2000 цитирований: 97
Pyrromethene–BF2 complexes as laser dyes: 2
Boyer J.H., Haag A.M., Sathyamoorthi G., Soong M., Thangaraj K., Pavlopoulos T.G.
Q3 Heteroatom Chemistry 1993 цитирований: 152
Open Access
Open access
Quenching of luminescence by oxygen
Kautsky H.
Transactions of the Faraday Society 1939 цитирований: 287
Метрики

Поделиться

Цитировать
ГОСТ |
Цитировать
1. Nuraneeva E. N. и др. Effect of Structure and Medium on Photostability of Halogenated Boron(III), Zinc(II), and Cadmium(II) Dipyrromethenates // Russian Journal of General Chemistry. 2018. Т. 88. № 6. С. 1172–1179.
RIS |
Цитировать

TY - JOUR

DO - 10.1134/s1070363218060208

UR - http://dx.doi.org/10.1134/S1070363218060208

TI - Effect of Structure and Medium on Photostability of Halogenated Boron(III), Zinc(II), and Cadmium(II) Dipyrromethenates

T2 - Russian Journal of General Chemistry

AU - Nuraneeva, E. N.

AU - Antina, E. V.

AU - Guseva, G. B.

AU - Berezin, M. B.

AU - V’yugin, A. I.

PY - 2018

DA - 2018/06

PB - Pleiades Publishing Ltd

SP - 1172-1179

IS - 6

VL - 88

SN - 1070-3632

SN - 1608-3350

ER -

BibTex |
Цитировать

@article{Nuraneeva_2018,

doi = {10.1134/s1070363218060208},

url = {https://doi.org/10.1134%2Fs1070363218060208},

year = 2018,

month = {jun},

publisher = {Pleiades Publishing Ltd},

volume = {88},

number = {6},

pages = {1172--1179},

author = {E. N. Nuraneeva and E. V. Antina and G. B. Guseva and M. B. Berezin and A. I. V'yugin},

title = {Effect of Structure and Medium on Photostability of Halogenated Boron({III}), Zinc({II}), and Cadmium({II}) Dipyrromethenates},

journal = {Russian Journal of General Chemistry}

}

MLA
Цитировать
Nuraneeva, E. N., et al. “Effect of Structure and Medium on Photostability of Halogenated Boron(III), Zinc(II), and Cadmium(II) Dipyrromethenates.” Russian Journal of General Chemistry, vol. 88, no. 6, June 2018, pp. 1172–79. Crossref, https://doi.org/10.1134/s1070363218060208.