Features of the Formation of the [(O)VIV(C2 O4 )(Phen)(H2 O)] Complex in the Malic Acid Oxidation Process
N. S. Panina
1
,
E M Nikandrov
1
,
A V Laptenkova
2
,
A A Selyutin
2
,
D O Ruzanov
1
,
A. N. Belyaev
1
1
Publication type: Journal Article
Publication date: 2019-04-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Complex [(O)VIV(C2O4)(Phen)(H2O)] was obtained on the basis of V2O5 and malic acid in the presence of concentrated HNO3 and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the $$\rm{VO}^+_2$$VO2+ and VO2+ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)CH2-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with VO2+.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Russian Chemical Bulletin
1 publication, 100%
|
|
|
1
|
Publishers
|
1
|
|
|
Springer Nature
1 publication, 100%
|
|
|
1
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
1
Total citations:
1
Citations from 2024:
1
(100%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Panina N. S. et al. Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process // Russian Journal of General Chemistry. 2019. Vol. 89. No. 4. pp. 741-746.
GOST all authors (up to 50)
Copy
Panina N. S., Nikandrov E. M., Laptenkova A. V., Selyutin A. A., Ruzanov D. O., Belyaev A. N. Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process // Russian Journal of General Chemistry. 2019. Vol. 89. No. 4. pp. 741-746.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1070363219040170
UR - https://doi.org/10.1134/S1070363219040170
TI - Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process
T2 - Russian Journal of General Chemistry
AU - Panina, N. S.
AU - Nikandrov, E M
AU - Laptenkova, A V
AU - Selyutin, A A
AU - Ruzanov, D O
AU - Belyaev, A. N.
PY - 2019
DA - 2019/04/01
PB - Pleiades Publishing
SP - 741-746
IS - 4
VL - 89
SN - 1070-3632
SN - 1608-3350
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Panina,
author = {N. S. Panina and E M Nikandrov and A V Laptenkova and A A Selyutin and D O Ruzanov and A. N. Belyaev},
title = {Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process},
journal = {Russian Journal of General Chemistry},
year = {2019},
volume = {89},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S1070363219040170},
number = {4},
pages = {741--746},
doi = {10.1134/S1070363219040170}
}
Cite this
MLA
Copy
Panina, N. S., et al. “Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process.” Russian Journal of General Chemistry, vol. 89, no. 4, Apr. 2019, pp. 741-746. https://doi.org/10.1134/S1070363219040170.
Profiles