Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment
Publication type: Journal Article
Publication date: 2019-10-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
The reaction of bis(cyclohexylisocyanide) complex of Pd(II) with substituted benzo[d]thiazole-2-amines in the presence of triethanolamine as the base has lead to the formation of deprotonated C,N-chelated carbene complexes with a structure similar to that described previously for the products of the reaction with unsubstituted benzo[d]thiazole-2-amine. The complexes have been isolated and characterized using high-resolution mass spectrometry, IR and NMR spectroscopy (1H, 13C{1H}, 1H-1H COSY, 1H-1H NOESY, 1H-13C HSQC, 1H-13C HMBC). The resulting complexes have exhibited moderate antibacterial activity against sensitive strains of gram-negative bacteria E. coli (C600) and P. fluorescens (P218), gram-positive bacteria S. aureus (ATCC-25923) and B. subtillis (B-3142D) as well as fungi C. albicans (401/NCTC-885-653).
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Total citations:
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Citations from 2024:
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(16.67%)
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Mikherdov A. S. et al. Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment // Russian Journal of General Chemistry. 2019. Vol. 89. No. 10. pp. 2062-2068.
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Mikherdov A. S., Baikov S. V., Proskurina I. K., Shetnev A. A., Kotov A. D. Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment // Russian Journal of General Chemistry. 2019. Vol. 89. No. 10. pp. 2062-2068.
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TY - JOUR
DO - 10.1134/S1070363219100128
UR - https://doi.org/10.1134/S1070363219100128
TI - Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment
T2 - Russian Journal of General Chemistry
AU - Mikherdov, A S
AU - Baikov, S V
AU - Proskurina, I K
AU - Shetnev, A A
AU - Kotov, A D
PY - 2019
DA - 2019/10/01
PB - Pleiades Publishing
SP - 2062-2068
IS - 10
VL - 89
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2019_Mikherdov,
author = {A S Mikherdov and S V Baikov and I K Proskurina and A A Shetnev and A D Kotov},
title = {Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment},
journal = {Russian Journal of General Chemistry},
year = {2019},
volume = {89},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S1070363219100128},
number = {10},
pages = {2062--2068},
doi = {10.1134/S1070363219100128}
}
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Mikherdov, A. S., et al. “Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment.” Russian Journal of General Chemistry, vol. 89, no. 10, Oct. 2019, pp. 2062-2068. https://doi.org/10.1134/S1070363219100128.
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