Russian Journal of General Chemistry, volume 90, issue 4, pages 640-647
Influence of the Mechanism of the Initial Stages of the Ligand Decomposition on the Initiating Ability of Cobalt(III) Ammine Tetrazolate Complexes
Publication type: Journal Article
Publication date: 2020-04-01
Journal:
Russian Journal of General Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.9
ISSN: 10703632, 16083350
General Chemistry
Abstract
The results of quantum chemical calculations for isolated molecules of pentaammine-(5-cyano-2H-tetrazolato-N2)cobalt(III) perchlorate, pentaammine-(5-nitrotetrazolato-N2)cobalt(III) perchlorate, tetraammine-cis-bis(5-nitro-2H-tetrazolato-N2)cobalt(III) perchlorate, and tetraammine-cis-bis(1-methyl-5-aminotetrazolo-N3,N4)cobalt(III) perchlorate, as well as of the products of their possible initial decomposition stage were presented. The energetics and pathways of such reactions were determined. For the first time with the use of quantum chemical calculations it was shown that the decomposition of cobalt amminates can start with destruction of the tetrazole ligand and elimination of molecular nitrogen, rather than with dissociation of the coordinated ammonia molecule from the inner sphere of the cobalt(III) complex. The activation and dissociation energies of these processes were determined.
Top-30
Citations by journals
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Inorganics
1 publication, 33.33%
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Russian Chemical Reviews
1 publication, 33.33%
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1
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Citations by publishers
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1
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Wiley
1 publication, 33.33%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 33.33%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 33.33%
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1
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Ilyushin M. A. et al. Influence of the Mechanism of the Initial Stages of the Ligand Decomposition on the Initiating Ability of Cobalt(III) Ammine Tetrazolate Complexes // Russian Journal of General Chemistry. 2020. Vol. 90. No. 4. pp. 640-647.
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Ilyushin M. A., Shugalei I. V., Tverjanovich A. S., Smirnov A. V. Influence of the Mechanism of the Initial Stages of the Ligand Decomposition on the Initiating Ability of Cobalt(III) Ammine Tetrazolate Complexes // Russian Journal of General Chemistry. 2020. Vol. 90. No. 4. pp. 640-647.
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TY - JOUR
DO - 10.1134/s1070363220040131
UR - https://doi.org/10.1134/s1070363220040131
TI - Influence of the Mechanism of the Initial Stages of the Ligand Decomposition on the Initiating Ability of Cobalt(III) Ammine Tetrazolate Complexes
T2 - Russian Journal of General Chemistry
AU - Ilyushin, M A
AU - Shugalei, I V
AU - Tverjanovich, A. S.
AU - Smirnov, A. V.
PY - 2020
DA - 2020/04/01 00:00:00
PB - Pleiades Publishing
SP - 640-647
IS - 4
VL - 90
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2020_Ilyushin,
author = {M A Ilyushin and I V Shugalei and A. S. Tverjanovich and A. V. Smirnov},
title = {Influence of the Mechanism of the Initial Stages of the Ligand Decomposition on the Initiating Ability of Cobalt(III) Ammine Tetrazolate Complexes},
journal = {Russian Journal of General Chemistry},
year = {2020},
volume = {90},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/s1070363220040131},
number = {4},
pages = {640--647},
doi = {10.1134/s1070363220040131}
}
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MLA
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Ilyushin, M. A., et al. “Influence of the Mechanism of the Initial Stages of the Ligand Decomposition on the Initiating Ability of Cobalt(III) Ammine Tetrazolate Complexes.” Russian Journal of General Chemistry, vol. 90, no. 4, Apr. 2020, pp. 640-647. https://doi.org/10.1134/s1070363220040131.