Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole
Publication type: Journal Article
Publication date: 2020-06-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
A series of iridium complexes with various cyclometalated ligands and phosphines [Ir(N^C)2(PR3)Cl], where N^C = 2-(benzothiophen-3-yl)pyridine and 2-phenylpyridine and R = phenyl and p-methoxyphenyl, were obtained. It was shown that the complexes of this type react with imidazole under mild conditions. The phosphine and chloride ligands are consecutively substituted to give imidazole-containing derivatives. The photophysical properties of all the synthesized compounds were investigated in detail. The imidazole-containing complexes demonstrate efficient triplet luminescence in solution with quantum yields up to 60%, which is sensitive to molecular oxygen.
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Chapaikina S. A., Solomatina A. I., Tunik S. P. Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole // Russian Journal of General Chemistry. 2020. Vol. 90. No. 6. pp. 1005-1011.
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Chapaikina S. A., Solomatina A. I., Tunik S. P. Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole // Russian Journal of General Chemistry. 2020. Vol. 90. No. 6. pp. 1005-1011.
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TY - JOUR
DO - 10.1134/S1070363220060110
UR - https://doi.org/10.1134/S1070363220060110
TI - Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole
T2 - Russian Journal of General Chemistry
AU - Chapaikina, S A
AU - Solomatina, A I
AU - Tunik, S P
PY - 2020
DA - 2020/06/01
PB - Pleiades Publishing
SP - 1005-1011
IS - 6
VL - 90
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2020_Chapaikina,
author = {S A Chapaikina and A I Solomatina and S P Tunik},
title = {Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole},
journal = {Russian Journal of General Chemistry},
year = {2020},
volume = {90},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070363220060110},
number = {6},
pages = {1005--1011},
doi = {10.1134/S1070363220060110}
}
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Chapaikina, S. A., et al. “Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole.” Russian Journal of General Chemistry, vol. 90, no. 6, Jun. 2020, pp. 1005-1011. https://doi.org/10.1134/S1070363220060110.
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