Composition and Structure of Complexes Formed in GeCl4 –2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2 –Methanol
1
Mechnikov Odessa National University, Odessa, Ukraine
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Publication type: Journal Article
Publication date: 2020-12-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Tetrachlorozincates [Ge(LH)2][ZnCl4]∙CH3OH were isolated for the first time from isonicotinoylhydrazone 2-hydroxybenzene (2-hydroxynaphyl-1)carbaldehyde (H2L)–GeCl4–ZnCl2–CH3OH systems, in which cations are [Ge(L·H)2]2+ complexes protonated by the pyridine nitrogen atom, with L ligands tridentately coordinated via the azomethine nitrogen atom and oxygen atoms of deprotonated hydroxyazino and hydroxy groups. The complexes were studied using the methods of conductometry, thermogravimetry, IR, and 1H NMR spectroscopy.
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Shmatkova N. V. et al. Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol // Russian Journal of General Chemistry. 2020. Vol. 90. No. 12. pp. 2323-2327.
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Shmatkova N. V., Seifullina I. I., Skorokhod L. S., Morozov A. N., POPOV L., Gazieva G. A. Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol // Russian Journal of General Chemistry. 2020. Vol. 90. No. 12. pp. 2323-2327.
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TY - JOUR
DO - 10.1134/S1070363220120154
UR - http://link.springer.com/10.1134/S1070363220120154
TI - Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol
T2 - Russian Journal of General Chemistry
AU - Shmatkova, N V
AU - Seifullina, I I
AU - Skorokhod, L S
AU - Morozov, A. N.
AU - POPOV, L.D.
AU - Gazieva, G A
PY - 2020
DA - 2020/12/01
PB - Pleiades Publishing
SP - 2323-2327
IS - 12
VL - 90
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2020_Shmatkova,
author = {N V Shmatkova and I I Seifullina and L S Skorokhod and A. N. Morozov and L.D. POPOV and G A Gazieva},
title = {Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol},
journal = {Russian Journal of General Chemistry},
year = {2020},
volume = {90},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S1070363220120154},
number = {12},
pages = {2323--2327},
doi = {10.1134/S1070363220120154}
}
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Shmatkova, N. V., et al. “Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol.” Russian Journal of General Chemistry, vol. 90, no. 12, Dec. 2020, pp. 2323-2327. http://link.springer.com/10.1134/S1070363220120154.
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