Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?
K V Zaitsev
1
,
Yu F Oprunenko
1
Publication type: Journal Article
Publication date: 2021-12-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Reactions of 1-(chloromethyl)silatrane with organic group 14 element anions [(Me3Si)3E]‒ (E = Si, Ge) generated in situ afforded the corresponding substitution products (Me3Si)3ECH2Si(OCH2CH2)3N, whereas no products of ring-expansion rearrangement were detected. The structure of the isolated compounds was determined by multinuclear NMR spectroscopy.
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Zaitsev K. V. et al. Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement? // Russian Journal of General Chemistry. 2021. Vol. 91. No. 12. pp. 2385-2390.
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Zaitsev K. V., Oprunenko Yu. F. Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement? // Russian Journal of General Chemistry. 2021. Vol. 91. No. 12. pp. 2385-2390.
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TY - JOUR
DO - 10.1134/S1070363221120057
UR - https://link.springer.com/10.1134/S1070363221120057
TI - Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?
T2 - Russian Journal of General Chemistry
AU - Zaitsev, K V
AU - Oprunenko, Yu F
PY - 2021
DA - 2021/12/01
PB - Pleiades Publishing
SP - 2385-2390
IS - 12
VL - 91
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2021_Zaitsev,
author = {K V Zaitsev and Yu F Oprunenko},
title = {Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?},
journal = {Russian Journal of General Chemistry},
year = {2021},
volume = {91},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://link.springer.com/10.1134/S1070363221120057},
number = {12},
pages = {2385--2390},
doi = {10.1134/S1070363221120057}
}
Cite this
MLA
Copy
Zaitsev, K. V., et al. “Reaction of Substituted Group 14 Element Potassium Salts with 1-(Chloromethyl)silatrane: Substitution or Rearrangement?.” Russian Journal of General Chemistry, vol. 91, no. 12, Dec. 2021, pp. 2385-2390. https://link.springer.com/10.1134/S1070363221120057.
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