Russian Journal of General Chemistry, volume 92, issue 6, pages 1011-1031

Synthesis, Structure, and Spectral Properties of Metal Complexes Based on Isonicotinic Acid N′-(10-Oxo-10H-phenanthren-9-ylidene)hydrazide

Publication type: Journal Article
Publication date: 2022-06-01
Quartile SCImago
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Quartile WOS
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Impact factor: 0.9
ISSN: 10703632, 16083350
General Chemistry
Abstract
Isonicotinic acid N′-(10-oxo-10H-phenanthren-9-ylidene)hydrazide (HL) and its complexes ML2 and MHLCl2 [М = Cu(II), Ni(II), Co(II), Fe(II), and Zn(II)] were synthesized. The structure and properties of the obtained compounds were studied by 1H NMR, IR, and X-ray absorption spectroscopy. The hydrazide structure was determined by X-ray diffraction. Quantum-chemical calculations of its tautomeric forms and electronic absorption spectra were carried out. In ML2 chelate complexes, the ligand is coordinated to metal atoms in the enol form, whereas in MHLCl2 complexes it is coordinated in the keto form.
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Zaichenko S. B. et al. Synthesis, Structure, and Spectral Properties of Metal Complexes Based on Isonicotinic Acid N′-(10-Oxo-10H-phenanthren-9-ylidene)hydrazide // Russian Journal of General Chemistry. 2022. Vol. 92. No. 6. pp. 1011-1031.
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Zaichenko S. B., Popov L. E., Burlov A., Vlasenko V. G., Kolodina A. A., Korshunova E. V., Borodkin G. S., Khramov E., Demidov O. P., Shcherbakov I. N. Synthesis, Structure, and Spectral Properties of Metal Complexes Based on Isonicotinic Acid N′-(10-Oxo-10H-phenanthren-9-ylidene)hydrazide // Russian Journal of General Chemistry. 2022. Vol. 92. No. 6. pp. 1011-1031.
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TY - JOUR
DO - 10.1134/S1070363222060135
UR - https://doi.org/10.1134%2FS1070363222060135
TI - Synthesis, Structure, and Spectral Properties of Metal Complexes Based on Isonicotinic Acid N′-(10-Oxo-10H-phenanthren-9-ylidene)hydrazide
T2 - Russian Journal of General Chemistry
AU - Zaichenko, S B
AU - Popov, L. E.
AU - Burlov, A.S
AU - Vlasenko, Valery Grigorievich
AU - Kolodina, Alexandra A.
AU - Korshunova, E V
AU - Borodkin, G S
AU - Khramov, E. V.
AU - Shcherbakov, Igor N.
AU - Demidov, O P
PY - 2022
DA - 2022/06/01 00:00:00
PB - Pleiades Publishing
SP - 1011-1031
IS - 6
VL - 92
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2022_Zaichenko,
author = {S B Zaichenko and L. E. Popov and A.S Burlov and Valery Grigorievich Vlasenko and Alexandra A. Kolodina and E V Korshunova and G S Borodkin and E. V. Khramov and Igor N. Shcherbakov and O P Demidov},
title = {Synthesis, Structure, and Spectral Properties of Metal Complexes Based on Isonicotinic Acid N′-(10-Oxo-10H-phenanthren-9-ylidene)hydrazide},
journal = {Russian Journal of General Chemistry},
year = {2022},
volume = {92},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134%2FS1070363222060135},
number = {6},
pages = {1011--1031},
doi = {10.1134/S1070363222060135}
}
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Zaichenko, S. B., et al. “Synthesis, Structure, and Spectral Properties of Metal Complexes Based on Isonicotinic Acid N′-(10-Oxo-10H-phenanthren-9-ylidene)hydrazide.” Russian Journal of General Chemistry, vol. 92, no. 6, Jun. 2022, pp. 1011-1031. https://doi.org/10.1134%2FS1070363222060135.
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