Russian Journal of General Chemistry, volume 92, issue 6, pages 1032-1039
Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2 L1), Acetoacetanilide Benzoylhydrazone (H2 L2), and MoO2 L1·MeOH Solvate
Publication type: Journal Article
Publication date: 2022-06-01
Journal:
Russian Journal of General Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.9
ISSN: 10703632, 16083350
General Chemistry
Abstract
Two acetylhydrazones, namely benzoylacetone nicotinoylhydrazone (H2L1) and acetoacetanilide benzoylhydrazone (H2L2), and also the MoO2L1·MeOH solvate complex were synthesized and their structure was studied by single crystal X-ray diffraction and IR-spectroscopy methods. Molecules of two hydrazones crystallize in different enehydrazonic tautomeric forms: hydrazonic for H2L1 and enehydrazine-α-oxyazine for H2L2. In the both organic molecules, two planar six-membered aromatic cycles are connected by zigzag six- and seven-membered C–C–C–N–N(H)–C– and –N–C–C–C–C–N–N–C– chains, respectively. The both organic molecules are stabilized by N–H···O intermolecular hydrogen bonds (and also by N–H···O intramolecular hydrogen bond in the H2L2 structure). In the MoO2L1·MeOH solvate, the molybdenum atom has an octahedral coordination environment formed by two cis-O2(oxo) and tridentate (ONO)bis(chelate) (L2)2– ligands, and also a methanol molecule. Atoms N(L1) and O(MeOH) are in trans-position to O(oxo); two atoms O(L1)—in cis-position to O(oxo) and trans-position to each other.
Citations by journals
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1
2
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Crystallography Reports
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Crystallography Reports
2 publications, 66.67%
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Polyhedron
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Polyhedron
1 publication, 33.33%
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Citations by publishers
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Pleiades Publishing
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Pleiades Publishing
2 publications, 66.67%
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Elsevier
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Elsevier
1 publication, 33.33%
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2
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Sergienko V. S. et al. Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2L1), Acetoacetanilide Benzoylhydrazone (H2L2), and MoO2L1·MeOH Solvate // Russian Journal of General Chemistry. 2022. Vol. 92. No. 6. pp. 1032-1039.
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Sergienko V. S., Abramenko V. L., Churakov A. V., Surashskaya M. D. Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2L1), Acetoacetanilide Benzoylhydrazone (H2L2), and MoO2L1·MeOH Solvate // Russian Journal of General Chemistry. 2022. Vol. 92. No. 6. pp. 1032-1039.
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TY - JOUR
DO - 10.1134/S1070363222060147
UR - https://doi.org/10.1134%2FS1070363222060147
TI - Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2L1), Acetoacetanilide Benzoylhydrazone (H2L2), and MoO2L1·MeOH Solvate
T2 - Russian Journal of General Chemistry
AU - Sergienko, V S
AU - Abramenko, V L
AU - Churakov, Andrei V.
AU - Surashskaya, M D
PY - 2022
DA - 2022/06/01 00:00:00
PB - Pleiades Publishing
SP - 1032-1039
IS - 6
VL - 92
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2022_Sergienko,
author = {V S Sergienko and V L Abramenko and Andrei V. Churakov and M D Surashskaya},
title = {Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2L1), Acetoacetanilide Benzoylhydrazone (H2L2), and MoO2L1·MeOH Solvate},
journal = {Russian Journal of General Chemistry},
year = {2022},
volume = {92},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134%2FS1070363222060147},
number = {6},
pages = {1032--1039},
doi = {10.1134/S1070363222060147}
}
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Sergienko, V. S., et al. “Synthesis and Structure of Dioxomolibdenum(VI) Complexes with Hydrazones of β-Dicarbonyl Compounds. Crystal Structures of Benzoylacetone Nicotinoylhydrazone (H2L1), Acetoacetanilide Benzoylhydrazone (H2L2), and MoO2L1·MeOH Solvate.” Russian Journal of General Chemistry, vol. 92, no. 6, Jun. 2022, pp. 1032-1039. https://doi.org/10.1134%2FS1070363222060147.