Kinetics and Mechanism of the Reaction of Triphenylphosphine with Methyl Vinyl Ketone
Тип публикации: Journal Article
Дата публикации: 2022-07-01
SCImago Q4
WOS Q4
БС2
SJR: 0.205
CiteScore: 1.6
Impact factor: 1
ISSN: 10703632, 16083350
General Chemistry
Краткое описание
Kinetics of the reaction of triphenylphosphine with methyl vinyl ketone has been studied using the stopped flow technique. The experimental data have indicated that the reactions of alkenes activated by different electron withdrawing groups belong to the same reaction series and follow the identical mechanism involving the rate-determining proton transfer step. The effect of the electron withdrawing groups has been quantitatively analyzed using various relationships, and no correlation between the electrophilicity and the alkene reactivity has been found.
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Salin A. V., Shabanov A. A., Karamaeva T. V. Kinetics and Mechanism of the Reaction of Triphenylphosphine with Methyl Vinyl Ketone // Russian Journal of General Chemistry. 2022. Vol. 92. No. 7. pp. 1184-1189.
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Salin A. V., Shabanov A. A., Karamaeva T. V. Kinetics and Mechanism of the Reaction of Triphenylphosphine with Methyl Vinyl Ketone // Russian Journal of General Chemistry. 2022. Vol. 92. No. 7. pp. 1184-1189.
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TY - JOUR
DO - 10.1134/s1070363222070027
UR - https://doi.org/10.1134/s1070363222070027
TI - Kinetics and Mechanism of the Reaction of Triphenylphosphine with Methyl Vinyl Ketone
T2 - Russian Journal of General Chemistry
AU - Salin, Alexey V.
AU - Shabanov, A A
AU - Karamaeva, T V
PY - 2022
DA - 2022/07/01
PB - Pleiades Publishing
SP - 1184-1189
IS - 7
VL - 92
SN - 1070-3632
SN - 1608-3350
ER -
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@article{2022_Salin,
author = {Alexey V. Salin and A A Shabanov and T V Karamaeva},
title = {Kinetics and Mechanism of the Reaction of Triphenylphosphine with Methyl Vinyl Ketone},
journal = {Russian Journal of General Chemistry},
year = {2022},
volume = {92},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/s1070363222070027},
number = {7},
pages = {1184--1189},
doi = {10.1134/s1070363222070027}
}
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MLA
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Salin, Alexey V., et al. “Kinetics and Mechanism of the Reaction of Triphenylphosphine with Methyl Vinyl Ketone.” Russian Journal of General Chemistry, vol. 92, no. 7, Jul. 2022, pp. 1184-1189. https://doi.org/10.1134/s1070363222070027.
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