Oxidation of 2-Cyanothioacrylamides with Sodium Nitrite in Acidic Medium
P G Dahno
1
,
D M Zhilyaev
1
,
Viktor V Dotsenko
1, 2
,
V D Strelkov
1
,
G D Krapivin
3
,
Inna V. Aksenova
2
,
N G Likhovid
2
Publication type: Journal Article
Publication date: 2022-09-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
(E)-3-Aryl-2-cyanoprop-2-entioamides, prepared by Knoevenagel condensation between aromatic aldehydes and cyanothioacetamide, react with sodium nitrite in acetic acid to form (2E,2′E)-2,2′-(1,2,4-thiadiazole-3,5-diyl)bis[3-arylacrylonitriles]. A possible mechanism and limitations of the reaction are discussed. Molecular docking was carried out in order to search for possible protein targets for the obtained 1,2,4-thiadiazoles. One of the compounds showed a pronounced antidote effect against the herbicide 2,4-D in a laboratory experiment on sunflower seedlings and under field conditions.
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Total citations:
13
Citations from 2024:
4
(33.33%)
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GOST
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Dahno P. G. et al. Oxidation of 2-Cyanothioacrylamides with Sodium Nitrite in Acidic Medium // Russian Journal of General Chemistry. 2022. Vol. 92. No. 9. pp. 1667-1676.
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Dahno P. G., Zhilyaev D. M., Dotsenko V. V., Strelkov V. D., Krapivin G. D., Aksenov N. A., Aksenova I. V., Likhovid N. G. Oxidation of 2-Cyanothioacrylamides with Sodium Nitrite in Acidic Medium // Russian Journal of General Chemistry. 2022. Vol. 92. No. 9. pp. 1667-1676.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/s1070363222090080
UR - https://doi.org/10.1134/s1070363222090080
TI - Oxidation of 2-Cyanothioacrylamides with Sodium Nitrite in Acidic Medium
T2 - Russian Journal of General Chemistry
AU - Dahno, P G
AU - Zhilyaev, D M
AU - Dotsenko, Viktor V
AU - Strelkov, V D
AU - Krapivin, G D
AU - Aksenov, Nicolai A.
AU - Aksenova, Inna V.
AU - Likhovid, N G
PY - 2022
DA - 2022/09/01
PB - Pleiades Publishing
SP - 1667-1676
IS - 9
VL - 92
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2022_Dahno,
author = {P G Dahno and D M Zhilyaev and Viktor V Dotsenko and V D Strelkov and G D Krapivin and Nicolai A. Aksenov and Inna V. Aksenova and N G Likhovid},
title = {Oxidation of 2-Cyanothioacrylamides with Sodium Nitrite in Acidic Medium},
journal = {Russian Journal of General Chemistry},
year = {2022},
volume = {92},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/s1070363222090080},
number = {9},
pages = {1667--1676},
doi = {10.1134/s1070363222090080}
}
Cite this
MLA
Copy
Dahno, P. G., et al. “Oxidation of 2-Cyanothioacrylamides with Sodium Nitrite in Acidic Medium.” Russian Journal of General Chemistry, vol. 92, no. 9, Sep. 2022, pp. 1667-1676. https://doi.org/10.1134/s1070363222090080.