Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis
K N Iost
1
,
V L Temerev
1
,
N S Smirnova
2
,
D.A Shlyapin
1
,
V. A. Borisov
1, 3
,
I V Muromtsev
1
,
M V Trenikhin
1
,
T V Kireeva
1
,
A V Shilova
1
,
P.G Tsyrulnikov
1
Publication type: Journal Article
Publication date: 2017-06-01
scimago Q4
wos Q4
SJR: 0.191
CiteScore: 1.4
Impact factor: 0.6
ISSN: 10704272, 16083296
General Chemistry
General Chemical Engineering
Abstract
Ru–Ba–Cs/Sibunit ternary catalysts were synthesized. Their activity in ammonia synthesis and the thermal stability of the support in a reducing atmosphere at elevated temperature depend on the molar ratio of the promoters. The results of studies using physical methods suggest that cesium predominantly interacts with the support, acting as an electronic promoter, whereas barium is a structural promoter. The synergistic action of the promoters at increased barium content of the catalyst was revealed. The highest activity in ammonia synthesis, 34.5 mLNH3 gcat–1 h–1, was reached for the 4% Ru–10.8% Ba–2.6% Cs/Sibunit catalyst.
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GOST
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Iost K. N. et al. Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis // Russian Journal of Applied Chemistry. 2017. Vol. 90. No. 6. pp. 887-894.
GOST all authors (up to 50)
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Iost K. N., Temerev V. L., Smirnova N. S., Shlyapin D., Borisov V. A., Muromtsev I. V., Trenikhin M. V., Kireeva T. V., Shilova A. V., Tsyrulnikov P. Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis // Russian Journal of Applied Chemistry. 2017. Vol. 90. No. 6. pp. 887-894.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1070427217060088
UR - https://doi.org/10.1134/S1070427217060088
TI - Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis
T2 - Russian Journal of Applied Chemistry
AU - Iost, K N
AU - Temerev, V L
AU - Smirnova, N S
AU - Shlyapin, D.A
AU - Borisov, V. A.
AU - Muromtsev, I V
AU - Trenikhin, M V
AU - Kireeva, T V
AU - Shilova, A V
AU - Tsyrulnikov, P.G
PY - 2017
DA - 2017/06/01
PB - Pleiades Publishing
SP - 887-894
IS - 6
VL - 90
SN - 1070-4272
SN - 1608-3296
ER -
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BibTex (up to 50 authors)
Copy
@article{2017_Iost,
author = {K N Iost and V L Temerev and N S Smirnova and D.A Shlyapin and V. A. Borisov and I V Muromtsev and M V Trenikhin and T V Kireeva and A V Shilova and P.G Tsyrulnikov},
title = {Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis},
journal = {Russian Journal of Applied Chemistry},
year = {2017},
volume = {90},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070427217060088},
number = {6},
pages = {887--894},
doi = {10.1134/S1070427217060088}
}
Cite this
MLA
Copy
Iost, K. N., et al. “Synthesis and study of Ru–Ba–Cs/Sibunit ternary catalysts for ammonia synthesis.” Russian Journal of Applied Chemistry, vol. 90, no. 6, Jun. 2017, pp. 887-894. https://doi.org/10.1134/S1070427217060088.
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