Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2 O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene
D V Glyzdova
1
,
N S Smirnova
2
,
V L Temerev
1
,
E. V. Khramov
3
,
T I Gulyaeva
1
,
M V Trenikhin
1, 4, 5
,
D.A Shlyapin
1
,
P.G Tsyrulnikov
1
1
2
Publication type: Journal Article
Publication date: 2017-12-01
scimago Q4
wos Q4
SJR: 0.191
CiteScore: 1.4
Impact factor: 0.6
ISSN: 10704272, 16083296
General Chemistry
General Chemical Engineering
Abstract
Effect of the phase composition of aluminum oxide [γ- and (δ + θ) phase] and introduction of zinc additives on the catalytic properties of 0.5% Pd/Al2O3 systems in the reaction of liquid-phase hydrogenation of acetylene into ethylene under an elevated pressure in a flow-through mode was studied. An increase in the activity of the Pd catalyst upon modification with zinc is only observed in the case of a system supported by the mixed phase of (δ + θ) aluminum oxide. XAFS spectroscopy was used to find that the increase in the activity and selectivity with respect to ethylene (in the presence of carbon monoxide) on the (0.5% Pd–0.62% Zn)/(δ + θ)-Al2O3 catalyst is correlated with the formation of the PdZn intermetallic compound.
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Total citations:
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Citations from 2024:
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(30%)
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GOST
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Glyzdova D. V. et al. Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene // Russian Journal of Applied Chemistry. 2017. Vol. 90. No. 12. pp. 1908-1917.
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Glyzdova D. V., Smirnova N. S., Temerev V. L., Khramov E., Gulyaeva T. I., Trenikhin M. V., Shlyapin D., Tsyrulnikov P. Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene // Russian Journal of Applied Chemistry. 2017. Vol. 90. No. 12. pp. 1908-1917.
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RIS
Copy
TY - JOUR
DO - 10.1134/S1070427217120035
UR - https://doi.org/10.1134/S1070427217120035
TI - Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene
T2 - Russian Journal of Applied Chemistry
AU - Glyzdova, D V
AU - Smirnova, N S
AU - Temerev, V L
AU - Khramov, E. V.
AU - Gulyaeva, T I
AU - Trenikhin, M V
AU - Shlyapin, D.A
AU - Tsyrulnikov, P.G
PY - 2017
DA - 2017/12/01
PB - Pleiades Publishing
SP - 1908-1917
IS - 12
VL - 90
SN - 1070-4272
SN - 1608-3296
ER -
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BibTex (up to 50 authors)
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@article{2017_Glyzdova,
author = {D V Glyzdova and N S Smirnova and V L Temerev and E. V. Khramov and T I Gulyaeva and M V Trenikhin and D.A Shlyapin and P.G Tsyrulnikov},
title = {Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene},
journal = {Russian Journal of Applied Chemistry},
year = {2017},
volume = {90},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1070427217120035},
number = {12},
pages = {1908--1917},
doi = {10.1134/S1070427217120035}
}
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MLA
Copy
Glyzdova, D. V., et al. “Study of the Influence Exerted by Zinc Additive on the Structure and Catalytic Properties of Pd/Al2O3 Catalysts for Liquid-Phase Hydrogenation of Acetylene.” Russian Journal of Applied Chemistry, vol. 90, no. 12, Dec. 2017, pp. 1908-1917. https://doi.org/10.1134/S1070427217120035.