N-aryl- and N-vinyldiaza-18-crown-6: Synthesis and complexing ability
Publication type: Journal Article
Publication date: 2006-03-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
The nucleophilic aromatic and vinyl substitution using diaza-18-crown-6 as nucleophile afforded a number of its N,N’-diaryl-[aryl = 2,4-(NO2)2C6H3, 4-C5F4N, 4-CF3C6F4] and N,N’-dialkenyl-substituted derivatives [alkenyl = PhC(O)CH=CH, MeOCOCH=CH, (EtO2C)2C=C(Ph), etc.]. Arylation of diaza-18-crown-6 with nonactivated aryl bromides, such as 4-Me2NC6H4Br, 4-MeOC6H4Br, C6H5Br, and 4-CF3C6H4Br, was effected under catalysis by palladium complexes. N,N’-Diaryldiaza-18-crowns-6 having electron-acceptor substituents in the aromatic rings turned out to be incapable of forming complexes with metal cations, while their analogs containing electron-donor para-methoxy and para-dimethylamino groups gave complexes with barium perchlorate.
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Sazonov P., Artamkina G., Beletskaya I. P. N-aryl- and N-vinyldiaza-18-crown-6: Synthesis and complexing ability // Russian Journal of Organic Chemistry. 2006. Vol. 42. No. 3. pp. 438-447.
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Sazonov P., Artamkina G., Beletskaya I. P. N-aryl- and N-vinyldiaza-18-crown-6: Synthesis and complexing ability // Russian Journal of Organic Chemistry. 2006. Vol. 42. No. 3. pp. 438-447.
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TY - JOUR
DO - 10.1134/S1070428006030171
UR - https://doi.org/10.1134/S1070428006030171
TI - N-aryl- and N-vinyldiaza-18-crown-6: Synthesis and complexing ability
T2 - Russian Journal of Organic Chemistry
AU - Sazonov, P.K
AU - Artamkina, G.A
AU - Beletskaya, I P
PY - 2006
DA - 2006/03/01
PB - Pleiades Publishing
SP - 438-447
IS - 3
VL - 42
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2006_Sazonov,
author = {P.K Sazonov and G.A Artamkina and I P Beletskaya},
title = {N-aryl- and N-vinyldiaza-18-crown-6: Synthesis and complexing ability},
journal = {Russian Journal of Organic Chemistry},
year = {2006},
volume = {42},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S1070428006030171},
number = {3},
pages = {438--447},
doi = {10.1134/S1070428006030171}
}
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MLA
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Sazonov, P.K, et al. “N-aryl- and N-vinyldiaza-18-crown-6: Synthesis and complexing ability.” Russian Journal of Organic Chemistry, vol. 42, no. 3, Mar. 2006, pp. 438-447. https://doi.org/10.1134/S1070428006030171.
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