Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes
Publication type: Journal Article
Publication date: 2010-01-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Palladium-catalyzed amination of isomeric bromochloro- and dibromobenzenes with 1- and 2-aminoadamantanes was studied. The best yields of the corresponding monoamination products were obtained in the reactions of 2-aminoadamantane with bromochlorobenzenes. The arylation of 1-aminoadamantane was successful in the presence of donor phosphine ligand. The amination of o- and m-dibromobenzenes was strongly complicated by formation of diamination products. Conditions ensuring predominant formation of the latter were found. The arylation of 2-aminoadamantane was accompanied by oxidation of the initial amine and reduction of aryl halide.
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Averin A. D. et al. Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes // Russian Journal of Organic Chemistry. 2010. Vol. 46. No. 1. pp. 64-72.
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Averin A. D., Ulanovskaya M. A., Kovalev V. V., Buryak A., Orlinson B. S., Novakov I. A., Beletskaya I. P. Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes // Russian Journal of Organic Chemistry. 2010. Vol. 46. No. 1. pp. 64-72.
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RIS
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TY - JOUR
DO - 10.1134/S1070428010010069
UR - https://doi.org/10.1134/S1070428010010069
TI - Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes
T2 - Russian Journal of Organic Chemistry
AU - Averin, A D
AU - Ulanovskaya, M A
AU - Kovalev, V V
AU - Buryak, A.K
AU - Orlinson, B S
AU - Novakov, I A
AU - Beletskaya, I P
PY - 2010
DA - 2010/01/01
PB - Pleiades Publishing
SP - 64-72
IS - 1
VL - 46
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2010_Averin,
author = {A D Averin and M A Ulanovskaya and V V Kovalev and A.K Buryak and B S Orlinson and I A Novakov and I P Beletskaya},
title = {Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes},
journal = {Russian Journal of Organic Chemistry},
year = {2010},
volume = {46},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134/S1070428010010069},
number = {1},
pages = {64--72},
doi = {10.1134/S1070428010010069}
}
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MLA
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Averin, A. D., et al. “Palladium-catalyzed amination of isomeric dihalobenzenes with 1- and 2-aminoadamantanes.” Russian Journal of Organic Chemistry, vol. 46, no. 1, Jan. 2010, pp. 64-72. https://doi.org/10.1134/S1070428010010069.
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