volume 47 issue 7 pages 1101-1114

Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6

S N Dmitrieva 1
M V Churakova 1
N A Kurchavov 1
A.I. Vedernikov 1
A Ya Freidzon 1
S S Basok 2
A A Bagaturyants 1
2
 
Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
Publication typeJournal Article
Publication date2011-07-01
scimago Q4
wos Q4
SJR0.190
CiteScore1.3
Impact factor0.9
ISSN10704280, 16083393
Organic Chemistry
Abstract
A number of N-alkyl(nitrobenzo)aza-18-crowns-6 in which the nitrogen atom in the macroring is conjugated with the benzene ring were synthesized, and their complexing power was compared with that of model nitro derivatives of benzo-18-crown-6 and N-phenylaza-18-crown-6 using 1H NMR spectroscopy and DFT/PBE quantum-chemical calculations. The stability constants of the complexes formed by crown ethers with NH4/+, EtNH3/+, Li+, Na+, and K+ in CD3CN were determined by 1H NMR titration. The complexing power of N-alkyl(nitrobenzo)aza-18-crowns-6 toward metal and ammonium cation was considerably higher than that of N-(4-nitrophenyl)aza-18-crown-6 and N-alkyl(nitrobenzo)aza-15-crown-5 and was comparable or higher than that of nitrobenzo-18-crown-6.
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Dmitrieva S. N. et al. Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6 // Russian Journal of Organic Chemistry. 2011. Vol. 47. No. 7. pp. 1101-1114.
GOST all authors (up to 50) Copy
Dmitrieva S. N., Churakova M. V., Kurchavov N. A., Vedernikov A., Freidzon A. Ya., Basok S. S., Bagaturyants A. A., Gromov S. P. Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6 // Russian Journal of Organic Chemistry. 2011. Vol. 47. No. 7. pp. 1101-1114.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1070428011070220
UR - http://link.springer.com/10.1134/S1070428011070220
TI - Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6
T2 - Russian Journal of Organic Chemistry
AU - Dmitrieva, S N
AU - Churakova, M V
AU - Kurchavov, N A
AU - Vedernikov, A.I.
AU - Freidzon, A Ya
AU - Basok, S S
AU - Bagaturyants, A A
AU - Gromov, S P
PY - 2011
DA - 2011/07/01
PB - Pleiades Publishing
SP - 1101-1114
IS - 7
VL - 47
SN - 1070-4280
SN - 1608-3393
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Dmitrieva,
author = {S N Dmitrieva and M V Churakova and N A Kurchavov and A.I. Vedernikov and A Ya Freidzon and S S Basok and A A Bagaturyants and S P Gromov},
title = {Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6},
journal = {Russian Journal of Organic Chemistry},
year = {2011},
volume = {47},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S1070428011070220},
number = {7},
pages = {1101--1114},
doi = {10.1134/S1070428011070220}
}
MLA
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MLA Copy
Dmitrieva, S. N., et al. “Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6.” Russian Journal of Organic Chemistry, vol. 47, no. 7, Jul. 2011, pp. 1101-1114. http://link.springer.com/10.1134/S1070428011070220.
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