Russian Journal of Organic Chemistry

, том 47 , издание 7 , страницы 1101-1114

Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6

S N Dmitrieva ¹

M V Churakova ¹

N A Kurchavov ¹

A.I. Vedernikov ¹

A Ya Freidzon ¹

S S Basok ²

A A Bagaturyants ¹

S P Gromov ¹

Скрыть аффилиации авторов Показать аффилиации авторов: 2 аффилиации

Photochemistry center, Russian Academy of Sciences, Moscow, Russia |

Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine |

Тип публикации: Journal Article

Дата публикации: 2011-07-01

Pleiades Publishing

Russian Journal of Organic Chemistry

scimago Q4

wos Q4

БС3

SJR: 0.190

CiteScore: 1.3

Impact factor: 0.9

ISSN: 10704280, 16083393

DOI: 10.1134/S1070428011070220

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Organic Chemistry

Краткое описание

A number of N-alkyl(nitrobenzo)aza-18-crowns-6 in which the nitrogen atom in the macroring is conjugated with the benzene ring were synthesized, and their complexing power was compared with that of model nitro derivatives of benzo-18-crown-6 and N-phenylaza-18-crown-6 using 1H NMR spectroscopy and DFT/PBE quantum-chemical calculations. The stability constants of the complexes formed by crown ethers with NH4/+, EtNH3/+, Li+, Na+, and K+ in CD3CN were determined by 1H NMR titration. The complexing power of N-alkyl(nitrobenzo)aza-18-crowns-6 toward metal and ammonium cation was considerably higher than that of N-(4-nitrophenyl)aza-18-crown-6 and N-alkyl(nitrobenzo)aza-15-crown-5 and was comparable or higher than that of nitrobenzo-18-crown-6.

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Journal of Physical Organic Chemistry	Journal of Physical Organic Chemistry, 1, 16.67% Journal of Physical Organic Chemistry 1 публикация, 16.67%
Russian Chemical Bulletin	Russian Chemical Bulletin, 1, 16.67% Russian Chemical Bulletin 1 публикация, 16.67%
Langmuir	Langmuir, 1, 16.67% Langmuir 1 публикация, 16.67%
New Journal of Chemistry	New Journal of Chemistry, 1, 16.67% New Journal of Chemistry 1 публикация, 16.67%
RSC Advances	RSC Advances, 1, 16.67% RSC Advances 1 публикация, 16.67%
Russian Journal of Organic Chemistry	Russian Journal of Organic Chemistry, 1, 16.67% Russian Journal of Organic Chemistry 1 публикация, 16.67%
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Dmitrieva S. N. et al. Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6 // Russian Journal of Organic Chemistry. 2011. Vol. 47. No. 7. pp. 1101-1114.

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Dmitrieva S. N., Churakova M. V., Kurchavov N. A., Vedernikov A., Freidzon A. Ya., Basok S. S., Bagaturyants A. A., Gromov S. P. Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6 // Russian Journal of Organic Chemistry. 2011. Vol. 47. No. 7. pp. 1101-1114.

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TY - JOUR

DO - 10.1134/S1070428011070220

UR - http://link.springer.com/10.1134/S1070428011070220

TI - Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6

T2 - Russian Journal of Organic Chemistry

AU - Dmitrieva, S N

AU - Churakova, M V

AU - Kurchavov, N A

AU - Vedernikov, A.I.

AU - Freidzon, A Ya

AU - Basok, S S

AU - Bagaturyants, A A

AU - Gromov, S P

PY - 2011

DA - 2011/07/01

PB - Pleiades Publishing

SP - 1101-1114

IS - 7

VL - 47

SN - 1070-4280

SN - 1608-3393

ER -

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@article{2011_Dmitrieva,

author = {S N Dmitrieva and M V Churakova and N A Kurchavov and A.I. Vedernikov and A Ya Freidzon and S S Basok and A A Bagaturyants and S P Gromov},

title = {Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6},

journal = {Russian Journal of Organic Chemistry},

year = {2011},

volume = {47},

publisher = {Pleiades Publishing},

month = {jul},

url = {http://link.springer.com/10.1134/S1070428011070220},

number = {7},

pages = {1101--1114},

doi = {10.1134/S1070428011070220}

}

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Dmitrieva, S. N., et al. “Host-guest complexes of nitro-substituted N-alkylbenzoaza-18-crowns-6.” Russian Journal of Organic Chemistry, vol. 47, no. 7, Jul. 2011, pp. 1101-1114. http://link.springer.com/10.1134/S1070428011070220.