Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions
Тип публикации: Journal Article
Дата публикации: 2013-04-01
scimago Q4
wos Q4
БС3
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Краткое описание
Palladium(II) complexes with chelating and non-chelating diaminocarbene ligands were assessed as catalysts in the cross-coupling reactions of haloarenes with oct-1-yne (Sonogashira reaction) and phenylboronic acid (Suzuki reaction). Both complexes exhibited a higher catalytic activity than traditional phosphine ligandbased systems in the Sonogashira reaction, and they ensured cross-coupling not only with iodoarenes but also with bromoarenes activated by electron-withdrawing substituents. The catalytic activities of the examined complexes in the Suzuki reaction were appreciably different: the palladium(II) complex with the chelating ligand turned out to be considerably less active than the complex with the non-chelating ligand.
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Mikhailov V. N. et al. Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions // Russian Journal of Organic Chemistry. 2013. Vol. 49. No. 4. pp. 551-554.
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Mikhailov V. N., Savicheva E. A., Sorokoumov V. N., Boyarskii V. P. Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions // Russian Journal of Organic Chemistry. 2013. Vol. 49. No. 4. pp. 551-554.
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TY - JOUR
DO - 10.1134/S107042801304009X
UR - https://doi.org/10.1134/S107042801304009X
TI - Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions
T2 - Russian Journal of Organic Chemistry
AU - Mikhailov, V. N.
AU - Savicheva, E A
AU - Sorokoumov, V N
AU - Boyarskii, V P
PY - 2013
DA - 2013/04/01
PB - Pleiades Publishing
SP - 551-554
IS - 4
VL - 49
SN - 1070-4280
SN - 1608-3393
ER -
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@article{2013_Mikhailov,
author = {V. N. Mikhailov and E A Savicheva and V N Sorokoumov and V P Boyarskii},
title = {Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions},
journal = {Russian Journal of Organic Chemistry},
year = {2013},
volume = {49},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S107042801304009X},
number = {4},
pages = {551--554},
doi = {10.1134/S107042801304009X}
}
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MLA
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Mikhailov, V. N., et al. “Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions.” Russian Journal of Organic Chemistry, vol. 49, no. 4, Apr. 2013, pp. 551-554. https://doi.org/10.1134/S107042801304009X.