Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions
Publication type: Journal Article
Publication date: 2013-04-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Palladium(II) complexes with chelating and non-chelating diaminocarbene ligands were assessed as catalysts in the cross-coupling reactions of haloarenes with oct-1-yne (Sonogashira reaction) and phenylboronic acid (Suzuki reaction). Both complexes exhibited a higher catalytic activity than traditional phosphine ligandbased systems in the Sonogashira reaction, and they ensured cross-coupling not only with iodoarenes but also with bromoarenes activated by electron-withdrawing substituents. The catalytic activities of the examined complexes in the Suzuki reaction were appreciably different: the palladium(II) complex with the chelating ligand turned out to be considerably less active than the complex with the non-chelating ligand.
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13
Total citations:
13
Citations from 2024:
2
(15%)
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Mikhailov V. N. et al. Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions // Russian Journal of Organic Chemistry. 2013. Vol. 49. No. 4. pp. 551-554.
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Mikhailov V. N., Savicheva E. A., Sorokoumov V. N., Boyarskii V. P. Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions // Russian Journal of Organic Chemistry. 2013. Vol. 49. No. 4. pp. 551-554.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S107042801304009X
UR - https://doi.org/10.1134/S107042801304009X
TI - Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions
T2 - Russian Journal of Organic Chemistry
AU - Mikhailov, V. N.
AU - Savicheva, E A
AU - Sorokoumov, V N
AU - Boyarskii, V P
PY - 2013
DA - 2013/04/01
PB - Pleiades Publishing
SP - 551-554
IS - 4
VL - 49
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2013_Mikhailov,
author = {V. N. Mikhailov and E A Savicheva and V N Sorokoumov and V P Boyarskii},
title = {Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions},
journal = {Russian Journal of Organic Chemistry},
year = {2013},
volume = {49},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S107042801304009X},
number = {4},
pages = {551--554},
doi = {10.1134/S107042801304009X}
}
Cite this
MLA
Copy
Mikhailov, V. N., et al. “Catalytic activity of palladium(II) diaminocarbene complexes in the Sonogashira and Suzuki reactions.” Russian Journal of Organic Chemistry, vol. 49, no. 4, Apr. 2013, pp. 551-554. https://doi.org/10.1134/S107042801304009X.