Copper(I)-catalyzed amination of halothiophenes with polyamines
Publication type: Journal Article
Publication date: 2014-07-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
Copper(I)-catalyzed hetarylation of a series of polyamines and of 4,7,10-trioxatridecane-1,13-diamine with halothiophenes has been studied with a view to obtaining the corresponding N,N′-dihetaryl derivatives. The target products can be obtained using both 3-iodothiophene in the presence of CuI/L-proline/EtCN or CuI/N,N-dimethylglycine/EtCN as catalytic system and 3-bromothiophene in the system CuI/2-(2-methyl-1-oxopropyl)cyclohexanone/DMF. The latter system is also suitable for the hetarylation of 4,7,10-trioxatridecane-1,13-diamine with 3-iodothiophene. In some cases, N-(thiophen-3-yl) derivatives have also been isolated.
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Anokhin M. V. et al. Copper(I)-catalyzed amination of halothiophenes with polyamines // Russian Journal of Organic Chemistry. 2014. Vol. 50. No. 7. pp. 923-927.
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Anokhin M. V., Averin A. D., Panchenko S. P., Maloshitskaya O. A., Beletskaya I. P. Copper(I)-catalyzed amination of halothiophenes with polyamines // Russian Journal of Organic Chemistry. 2014. Vol. 50. No. 7. pp. 923-927.
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RIS
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TY - JOUR
DO - 10.1134/S107042801407001X
UR - https://doi.org/10.1134/S107042801407001X
TI - Copper(I)-catalyzed amination of halothiophenes with polyamines
T2 - Russian Journal of Organic Chemistry
AU - Anokhin, M V
AU - Averin, A D
AU - Panchenko, S P
AU - Maloshitskaya, O A
AU - Beletskaya, I P
PY - 2014
DA - 2014/07/01
PB - Pleiades Publishing
SP - 923-927
IS - 7
VL - 50
SN - 1070-4280
SN - 1608-3393
ER -
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BibTex (up to 50 authors)
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@article{2014_Anokhin,
author = {M V Anokhin and A D Averin and S P Panchenko and O A Maloshitskaya and I P Beletskaya},
title = {Copper(I)-catalyzed amination of halothiophenes with polyamines},
journal = {Russian Journal of Organic Chemistry},
year = {2014},
volume = {50},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S107042801407001X},
number = {7},
pages = {923--927},
doi = {10.1134/S107042801407001X}
}
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MLA
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Anokhin, M. V., et al. “Copper(I)-catalyzed amination of halothiophenes with polyamines.” Russian Journal of Organic Chemistry, vol. 50, no. 7, Jul. 2014, pp. 923-927. https://doi.org/10.1134/S107042801407001X.
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