volume 52 issue 8 pages 1126-1136

Oligoether derivatives of 1-phenoxyanthraquinone: Synthesis, photochromism, and complex formation with metal cations

Publication typeJournal Article
Publication date2016-08-01
scimago Q4
wos Q4
SJR0.190
CiteScore1.3
Impact factor0.9
ISSN10704280, 16083393
Organic Chemistry
Abstract
1-Phenoxyanthraquinone isomeric conjugates with tetraethylene glycol were prepared. Their photochromic properties and complex formation in solutions were quantitatively studied by spectrophotometry, quantum yields of the arylotropic photoisomerism and stability constants of complexes between para–ana-quinoid isomers and metal cations. The photochemical migration of a phenyl group considerably affects the complex stability thus providing the possibility to regard the synthesized compounds as photocontrolled ionophores. The structure of some complexes was investigated by X-ray diffraction (XRD) analysis and quantum-chemical simulation.
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Martyanov T. P., Klimenko L. S., Ushakov E. N. Oligoether derivatives of 1-phenoxyanthraquinone: Synthesis, photochromism, and complex formation with metal cations // Russian Journal of Organic Chemistry. 2016. Vol. 52. No. 8. pp. 1126-1136.
GOST all authors (up to 50) Copy
Martyanov T. P., Klimenko L. S., Ushakov E. N. Oligoether derivatives of 1-phenoxyanthraquinone: Synthesis, photochromism, and complex formation with metal cations // Russian Journal of Organic Chemistry. 2016. Vol. 52. No. 8. pp. 1126-1136.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/s1070428016080066
UR - https://doi.org/10.1134/s1070428016080066
TI - Oligoether derivatives of 1-phenoxyanthraquinone: Synthesis, photochromism, and complex formation with metal cations
T2 - Russian Journal of Organic Chemistry
AU - Martyanov, T P
AU - Klimenko, L S
AU - Ushakov, E N
PY - 2016
DA - 2016/08/01
PB - Pleiades Publishing
SP - 1126-1136
IS - 8
VL - 52
SN - 1070-4280
SN - 1608-3393
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Martyanov,
author = {T P Martyanov and L S Klimenko and E N Ushakov},
title = {Oligoether derivatives of 1-phenoxyanthraquinone: Synthesis, photochromism, and complex formation with metal cations},
journal = {Russian Journal of Organic Chemistry},
year = {2016},
volume = {52},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/s1070428016080066},
number = {8},
pages = {1126--1136},
doi = {10.1134/s1070428016080066}
}
MLA
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MLA Copy
Martyanov, T. P., et al. “Oligoether derivatives of 1-phenoxyanthraquinone: Synthesis, photochromism, and complex formation with metal cations.” Russian Journal of Organic Chemistry, vol. 52, no. 8, Aug. 2016, pp. 1126-1136. https://doi.org/10.1134/s1070428016080066.