Pleiades Publishing
Russian Journal of Organic Chemistry
,  том 53 ,  издание 11 ,  страницы 1726-1737

Synthesis, structure, spectral properties, and electrochemistry of bis(crown ether) containing 1,3-distyrylbenzenes

Тип публикации: Journal Article
Дата публикации: 2017-11-01
Pleiades Publishing
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SJR: 0.187
CiteScore: 1.3
Impact factor: 0.8
ISSN: 10704280, 16083393
Organic Chemistry
Краткое описание
The reaction of tetraethyl [1,3-phenylenedi(methylene)]bis(phosphonate) with formyl derivatives of benzocrown-ethers or formyl derivatives of o-dimethoxybenzene lead to high yield formation of the respectful bis(crown ether) containing 1,3-distyrylbenzenes or tetramethoxy-substituted 1,3-distyrenebenzenes. NMR spectra and quantum-chemical calculations showed the prevalence of unsymmetrical syn/anti,(syn,anti),syn/anti-conformations in 1,3-distyrylbenzenes. 1,3-Distyrylbenzenes absorb in shorter wavelength spectral region and have a weaker fluorescence than 1,4-distyrylbenzenes. The difficulty in the electrochemical reduction of 1,3-distyrylbenzenes comparing with 1,4-distyrylbenzenes is due to a less effective conjugation system in the metaderivatives.
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Nuriev V. N. et al. Synthesis, structure, spectral properties, and electrochemistry of bis(crown ether) containing 1,3-distyrylbenzenes // Russian Journal of Organic Chemistry. 2017. Vol. 53. No. 11. pp. 1726-1737.
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Nuriev V. N., Fedorov O., Moiseeva A. A., Freidzon A. Ya., Kurchavov N. A., Vedernikov A., Medvedko A. V., Podyacheva E. S., Vatsadze S. Z., Gromov S. P. Synthesis, structure, spectral properties, and electrochemistry of bis(crown ether) containing 1,3-distyrylbenzenes // Russian Journal of Organic Chemistry. 2017. Vol. 53. No. 11. pp. 1726-1737.
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TY - JOUR
DO - 10.1134/S1070428017110203
UR - http://link.springer.com/10.1134/S1070428017110203
TI - Synthesis, structure, spectral properties, and electrochemistry of bis(crown ether) containing 1,3-distyrylbenzenes
T2 - Russian Journal of Organic Chemistry
AU - Nuriev, V N
AU - Fedorov, O.V.
AU - Moiseeva, A A
AU - Freidzon, A Ya
AU - Kurchavov, N A
AU - Vedernikov, A.I.
AU - Medvedko, A V
AU - Podyacheva, E S
AU - Vatsadze, Sergey Z
AU - Gromov, S P
PY - 2017
DA - 2017/11/01
PB - Pleiades Publishing
SP - 1726-1737
IS - 11
VL - 53
SN - 1070-4280
SN - 1608-3393
ER -
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@article{2017_Nuriev,
author = {V N Nuriev and O.V. Fedorov and A A Moiseeva and A Ya Freidzon and N A Kurchavov and A.I. Vedernikov and A V Medvedko and E S Podyacheva and Sergey Z Vatsadze and S P Gromov},
title = {Synthesis, structure, spectral properties, and electrochemistry of bis(crown ether) containing 1,3-distyrylbenzenes},
journal = {Russian Journal of Organic Chemistry},
year = {2017},
volume = {53},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S1070428017110203},
number = {11},
pages = {1726--1737},
doi = {10.1134/S1070428017110203}
}
MLA
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Nuriev, V. N., et al. “Synthesis, structure, spectral properties, and electrochemistry of bis(crown ether) containing 1,3-distyrylbenzenes.” Russian Journal of Organic Chemistry, vol. 53, no. 11, Nov. 2017, pp. 1726-1737. http://link.springer.com/10.1134/S1070428017110203.
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